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As a vital configuration in PIBs, the two\u2010phase interface, which refers to K\u2010ion diffusion from the electrolyte to the electrode surface (solid\u2013liquid interface) and K\u2010ion migration between different particles (solid\u2013solid interface), deeply determines the diffusion\/reaction kinetics and structural stability, thus significantly affecting the rate performance and cyclability. However, researches on two\u2010phase interface are still in its infancy and need further attentions. This review first starts from the fundamental understanding of solid\u2013liquid and solid\u2013solid interfaces to in\u2010depth analyzing the effect mechanism of different improvement strategies on them, such as optimization of electrolyte and binders, heterostructure design, modulation of interlayer spacing, etc. Afterward, the research progress of these improvement strategies is summarized comprehensively. Finally, the major challenges are proposed, and the corresponding solving strategies are presented. This review is expected to give an insight into the importance of two\u2010phase interface on diffusion\/reaction kinetics, and provides a guidance for developing other advanced anodes in PIBs.<\/jats:p>","DOI":"10.1002\/advs.202200683","type":"journal-article","created":{"date-parts":[[2022,5,9]],"date-time":"2022-05-09T09:42:16Z","timestamp":1652089336000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":97,"title":["Fundamental Understanding and Research Progress on the Interfacial Behaviors for Potassium\u2010Ion Battery Anode"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5821-2511","authenticated-orcid":false,"given":"Fei","family":"Yuan","sequence":"first","affiliation":[{"name":"Hebei Key Laboratory of Flexible Functional Materials School of Materials Science and Engineering Hebei University of Science and Technology  Shijiazhuang 050000 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