{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T13:45:37Z","timestamp":1791812737144,"version":"4.3.4"},"reference-count":60,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2022,6,16]],"date-time":"2022-06-16T00:00:00Z","timestamp":1655337600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100012818","name":"Comunidad de Madrid","doi-asserted-by":"publisher","award":["PEJD\u20102017\u2010PRE\/IND\u20104037"],"award-info":[{"award-number":["PEJD\u20102017\u2010PRE\/IND\u20104037"]}],"id":[{"id":"10.13039\/100012818","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100012818","name":"Comunidad de Madrid","doi-asserted-by":"publisher","award":["2018\u2010T1\/IND\u20101005"],"award-info":[{"award-number":["2018\u2010T1\/IND\u20101005"]}],"id":[{"id":"10.13039\/100012818","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2022,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The increasing environmental protection demand has prompted the development of passive thermal regulation systems that reduce temperature fluctuations in buildings. Here, it is demonstrated that the heat generated by the sun can trigger a spin crossover (SCO) in a molecule\u2010base material, resulting in a concomitant color variation (from pink to white) and a phase transition. This leads to a cooling effect with respect to other thermochromic materials. In addition, when the material is cooled, a dampening of the temperature decrease is produced. Therefore, these materials can potentially be implemented for passive temperature control in buildings. Furthermore, SCO materials are remarkably stable upon cycling and highly versatile, which allows for the design of compounds with properties tailored for the desired climatic conditions and comfortable temperature.<\/jats:p>","DOI":"10.1002\/advs.202202253","type":"journal-article","created":{"date-parts":[[2022,6,17]],"date-time":"2022-06-17T02:34:36Z","timestamp":1655433276000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Concomitant Thermochromic and Phase\u2010Change Effect in a Switchable Spin Crossover Material for Efficient Passive Control of Day and Night Temperature Fluctuations"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1929-4681","authenticated-orcid":false,"given":"Esther","family":"Resines\u2010Urien","sequence":"first","affiliation":[{"name":"IMDEA Nanociencia  C\/ Faraday 9 Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miguel \u00c1ngel Garc\u00eda","family":"Garc\u00eda\u2010Tu\u00f1\u00f3n","sequence":"additional","affiliation":[{"name":"Instituto de Cer\u00e1mica y Vidrio CSIC  C\/Kelsen s\/n Madrid 28240 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mar","family":"Garc\u00eda\u2010Hern\u00e1ndez","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia de Materiales de Madrid CSIC  C\/Sor Juana In\u00e9s de la Cruz, 3 Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jose Alberto","family":"Rodr\u00edguez\u2010Velamaz\u00e1n","sequence":"additional","affiliation":[{"name":"Institut Laue\u2010Langevin  71 avenue des Martyrs, BP 156 Grenoble Cedex 9 38042 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ana","family":"Espinosa","sequence":"additional","affiliation":[{"name":"IMDEA Nanociencia  C\/ Faraday 9 Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5426-7956","authenticated-orcid":false,"given":"Jose S\u00e1nchez","family":"Costa","sequence":"additional","affiliation":[{"name":"IMDEA Nanociencia  C\/ Faraday 9 Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6,16]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u201cThe Critical Role of Buildings Perspectives for the Clean Energy Transition \u2013 Analysis\u201d https:\/\/www.iea.org\/reports\/the\u2010critical\u2010role\u2010of\u2010buildings(accessed: November 2020)."},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1061664"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abe3692"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2019.113522"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2016.09.045"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.106440"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b05112"},{"key":"e_1_2_8_8_1","first-page":"1","volume":"2106090","author":"Liu S.","year":"2022","journal-title":"Adv. Sci."},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.3389\/fenrg.2021.800382"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200300378"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.renene.2003.12.021"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egyr.2021.04.056"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature13883"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat9513"},{"key":"e_1_2_8_15_1","first-page":"1","volume":"5","author":"Leroy A.","year":"2019","journal-title":"Sci. Adv."},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-20314-w"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijheatmasstransfer.2016.08.009"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.105971"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201202574"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201907307"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.10.005"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.10.006"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2016.03.036"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2015.10.128"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2016.04.084"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2020.118572"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2018.11.061"},{"key":"e_1_2_8_28_1","unstructured":"\u201cIMD New Delhi SFD current month extremes\u201d https:\/\/amssdelhi.gov.in\/(accessed: November 2021)."},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2009.01.004"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1080\/15567036.2018.1486910"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-020-70931-0"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma3125143"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QM00624J"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201647"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.03.024"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900666"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201402579"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200700559"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15042a"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702739"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15046d"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4835995"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201903750"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.98.224408"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201807334"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008076"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202000987"},{"key":"e_1_2_8_48_1","unstructured":"A.Bousseksou L.Salmon G.Moln\u00e1r C.Bergaud K.Ridier C.Quintero WO2021064094A1 2020."},{"key":"e_1_2_8_49_1","unstructured":"C.Ferlay O.Ceysson EP3095831A1 2016."},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc02606a"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/b501491c"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc11441g"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.9b04291"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC00267A"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17362-7"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201201121"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm00044a044"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0020706"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.csite.2021.101360"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1080\/15567036.2018.1550125"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202202253","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.202202253","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202202253","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T14:16:45Z","timestamp":1759760205000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202202253"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6,16]]},"references-count":60,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2022,8]]}},"alternative-id":["10.1002\/advs.202202253"],"URL":"https:\/\/doi.org\/10.1002\/advs.202202253","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6,16]]},"assertion":[{"value":"2022-04-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2202253"}}