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Herein, the synergic effect of a bifunctional lignin\u2010containing cellulose nanofiber (LCNF)\u2010MXene (LM) layer to stabilize the interface of zinc anode is reported. On one hand, the LCNF provides enough strength (43.7\u00a0MPa) at relative low porosity (52.2%) to enable the diffusion limited dendrite suppression, while, on the other hand, the MXene serves as a zinc gating layer, facilitating the zinc ion mobility, restricting the active water\/anions from degradation in the electrode\/electrolyte interface, and epitaxially guiding zinc deposition along (002) plane. Benefiting from the synergic effect of diffusion limited dendrite suppression and zinc gate, the LM layer enabled a high coulombic efficiency (CE) of 98.9% with a low overpotential of 43.1\u00a0mV at 1 mA cm<jats:sup>\u22122<\/jats:sup> in Zn\/\/Cu asymmetric cells. More importantly, Zn\/\/MnO<jats:sub>2<\/jats:sub> full cells with the LM layer achieve a high\u2010capacity retention of 90.0% for over 1000 cycles at 1 A g<jats:sup>\u22121<\/jats:sup>, much higher than the full cell without the protective layer (73.9% over 500 cycles). The work provides a new insight in designing a dendrite\u2010free zinc anode for long\u2010cycle\u2010life batteries.<\/jats:p>","DOI":"10.1002\/advs.202202380","type":"journal-article","created":{"date-parts":[[2022,7,7]],"date-time":"2022-07-07T19:29:54Z","timestamp":1657222194000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":81,"title":["Synergic Effect of Dendrite\u2010Free and Zinc Gating in Lignin\u2010Containing Cellulose Nanofibers\u2010MXene Layer Enabling Long\u2010Cycle\u2010Life Zinc Metal Batteries"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4168-8289","authenticated-orcid":false,"given":"Chaozheng","family":"Liu","sequence":"first","affiliation":[{"name":"Co\u2010Innovation Center of Efficient Processing and Utilization of Forest Resources College of Materials Science and Engineering Nanjing Forestry University  Nanjing 210000 P. R. 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