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However, the influence of oxidizing anolytes on the crossover and oxidization of ammonium during the electrolysis reaction remains unexplored. Here it is reported that the use of analytes containing halide ions (Cl<jats:sup>\u2212<\/jats:sup> and Br<jats:sup>\u2212<\/jats:sup>) can rapidly convert the ammonium into N<jats:sub>2<\/jats:sub>, which further intensifies the crossover of ammonium. Moreover, the extent of migration and oxidation of ammonium is found to be closely associated with external factors, such as applied potentials and the concentration of Cl<jats:sup>\u2212<\/jats:sup>. These findings demonstrate the profound impact of oxidizing anolytes on the electrochemical synthesis of ammonia. Based on these results, many prior reported ammonia yield rates are calibrated. This work emphasizes the significance of avoiding selection of anolytes that can oxidize ammonium, which is believed to promote further progress in electrochemical nitrogen fixation.<\/jats:p>","DOI":"10.1002\/advs.202204205","type":"journal-article","created":{"date-parts":[[2022,10,17]],"date-time":"2022-10-17T21:37:15Z","timestamp":1666042635000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Rigorous Assessment of Cl<sup>\u2212<\/sup>\u2010Based Anolytes on Electrochemical Ammonia Synthesis"],"prefix":"10.1002","volume":"9","author":[{"given":"Zengxiang","family":"Lv","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing University of Chemical Technology  Beijing 100029 P. R. 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