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The two essential parts, sorbent material and system structure, dominate the water sorption\u2013desorption performance and the total water productivity for SAWH system together. Attributed to the superiorities in aspects of sorption\u2013desorption performance, scalability, and compatibility in practical SAWH devices, hygroscopic porous polymers (HPPs) as next\u2010generation sorbents are recently going through a vast surge. However, as HPPs\u2019 sorption mechanism, performance, and applied potential lack comprehensive and accurate guidelines, SAWH's subsequent development is restricted. To address the aforementioned problems, this review introduces HPPs\u2019 recent development related to mechanism, performance, and application. Furthermore, corresponding optimized strategies for both HPP\u2010based sorbent bed and coupling structural design are proposed. Finally, original research routes are directed to develop next\u2010generation HPP\u2010based SAWH systems. The presented guidelines and insights can influence and inspire the future development of SAWH technology, further achieving SAWH's practical applications.<\/jats:p>","DOI":"10.1002\/advs.202204724","type":"journal-article","created":{"date-parts":[[2022,10,9]],"date-time":"2022-10-09T06:45:15Z","timestamp":1665297915000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":134,"title":["Hygroscopic Porous Polymer for Sorption\u2010Based Atmospheric Water Harvesting"],"prefix":"10.1002","volume":"9","author":[{"given":"Fangfang","family":"Deng","sequence":"first","affiliation":[{"name":"Institute of Refrigeration and Cryogenics MOE Engineering Research Center of Solar Power and Refrigeration Shanghai Jiao Tong University  Shanghai 200040 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihui","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Refrigeration and Cryogenics MOE 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