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Besides, they possess a polaron character due to the soft crystal lattice, which can prolong the spin lifetime, making them favorable materials for spintronic applications. Here, the spin dynamics of 2D PEA<jats:sub>2<\/jats:sub>PbI<jats:sub>4<\/jats:sub>(MAPbI<jats:sub>3<\/jats:sub>)<jats:italic><jats:sub>n<\/jats:sub><\/jats:italic><jats:sub>\u2212l<\/jats:sub> thin films with different layers by temperature\u2010 and pump fluence\u2013dependent circularly polarization\u2010resolved transient absorption (TA) measurements is studied. These results indicate that the spin depolarization mechanism is gradually converted from the Maialle\u2013Silva\u2013Sham (MSS) mechanism to the polaronic states protection mechanism with the layer number increasing from &lt;<jats:italic>n<\/jats:italic>&gt; = 1 to 3, which is determined by the interplay between the strength of Coulomb exchange interaction and the strength of polaronic effect. While for &lt;<jats:italic>n<\/jats:italic>&gt; \u2265 4, the Elliot\u2013Yafet (EY) impurities mechanism is proposed, in which the formed polaronic states with free charge carriers no longer play the protective role.<\/jats:p>","DOI":"10.1002\/advs.202302554","type":"journal-article","created":{"date-parts":[[2023,7,3]],"date-time":"2023-07-03T07:20:28Z","timestamp":1688368828000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["The Role of Polaronic States on the Spin Dynamics in Solution\u2010Processed Two\u2010Dimensional Layered Perovskite with Different Layer Thickness"],"prefix":"10.1002","volume":"10","author":[{"given":"Mu\u2010Sen","family":"Song","sequence":"first","affiliation":[{"name":"State Key Laboratory of Integrated Optoelectronics College of Electronic Science and Engineering Jilin University 2699 Qianjin Street Changchun 130012 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