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However, to realize a variety of organic optoelectronic devices, high\u2010performance n\u2010type polymer semiconductors are essential. Herein, conjugated microporous polymers (CMPs) comprising isoindigo acceptor units linked to benzene or pyrene donor units (<jats:bold>BI<\/jats:bold> and <jats:bold>PI<\/jats:bold>) showing n\u2010type semiconducting behavior are reported. In addition, considering the challenges of deposition of a continuous and homogeneous thin film of CMPs for accurate Hall measurements, a plasma\u2010assisted fabrication technique is developed to yield uniform thin films. The fully conjugated 2D networks in <jats:bold>PI<\/jats:bold>\u2010 and <jats:bold>BI<\/jats:bold>\u2010CMP films display high electron mobility of 6.6 and 3.5\u00a0cm<jats:sup>2<\/jats:sup> V<jats:sup>\u22121<\/jats:sup> s<jats:sup>\u22121<\/jats:sup>, respectively. The higher carrier concentration in <jats:bold>PI<\/jats:bold> results in high conductivity (5.3\u00a0mS\u00a0cm<jats:sup>\u22121<\/jats:sup>). Both experimental and computational studies are adequately combined to investigate structure\u2013property relations for this intriguing class of materials in the context of organic electronics.<\/jats:p>","DOI":"10.1002\/advs.202303562","type":"journal-article","created":{"date-parts":[[2023,8,21]],"date-time":"2023-08-21T09:56:28Z","timestamp":1692611788000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["A Rational Design of Isoindigo\u2010Based Conjugated Microporous <i>n<\/i>\u2010Type Semiconductors for High Electron Mobility and Conductivity"],"prefix":"10.1002","volume":"10","author":[{"given":"Kayaramkodath Chandran","family":"Ranjeesh","sequence":"first","affiliation":[{"name":"Department of Chemistry Khalifa University Abu Dhabi P.O. Box 127788 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4433-4446","authenticated-orcid":false,"given":"Ayman","family":"Rezk","sequence":"additional","affiliation":[{"name":"Department of Electrical Engineering and Computer Science Khalifa University Abu Dhabi P.O. Box 127788 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jose Ignacio","family":"Martinez","sequence":"additional","affiliation":[{"name":"Department of Low\u2010Dimensional Systems Instituto de Ciencia de Materiales de Madrid\u2010CSIC  C\/ Sor Juana In\u00e9s de la Cruz 3 Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Safa","family":"Gaber","sequence":"additional","affiliation":[{"name":"Department of Chemistry Khalifa University Abu Dhabi P.O. Box 127788 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Areej","family":"Merhi","sequence":"additional","affiliation":[{"name":"Department of Chemistry American University of Beirut  Beirut 1107\u20102020 Lebanon"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tina","family":"Skorjanc","sequence":"additional","affiliation":[{"name":"Materials Research Laboratory University of Nova Gorica  Vipavska cesta 11c Ajdovscina 5270 Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matja\u017e","family":"Fin\u0161gar","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Engineering University of Maribor  Smetanova ulica 17 Maribor 2000 Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gisha Elizabeth","family":"Luckachan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Khalifa University Abu Dhabi P.O. Box 127788 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ali","family":"Trabolsi","sequence":"additional","affiliation":[{"name":"Science Division New York University Abu Dhabi Saadiyat Island  Abu Dhabi P.O. Box 129188 UAE"},{"name":"NYUAD Water Research Center New York University Abu Dhabi (NYUAD) Saadiyat Island Abu Dhabi P.O. Box 129188 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1341-1963","authenticated-orcid":false,"given":"Bilal R.","family":"Kaafarani","sequence":"additional","affiliation":[{"name":"Department of Chemistry American University of Beirut  Beirut 1107\u20102020 Lebanon"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ammar","family":"Nayfeh","sequence":"additional","affiliation":[{"name":"Department of Electrical Engineering and Computer Science Khalifa University Abu Dhabi P.O. Box 127788 UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5456-0386","authenticated-orcid":false,"given":"Dinesh","family":"Shetty","sequence":"additional","affiliation":[{"name":"Department of Chemistry Khalifa University Abu Dhabi P.O. Box 127788 UAE"},{"name":"Advanced Materials Chemistry Center (AMCC) Khalifa University Abu Dhabi P.O. 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