{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T17:17:41Z","timestamp":1792603061241,"version":"4.5.0"},"reference-count":84,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2023,8,25]],"date-time":"2023-08-25T00:00:00Z","timestamp":1692921600000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2023,8,25]],"date-time":"2023-08-25T00:00:00Z","timestamp":1692921600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006224","name":"Argonne National Laboratory","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201006CH11357"],"award-info":[{"award-number":["DE\u2010AC02\u201006CH11357"]}],"id":[{"id":"10.13039\/100006224","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["22\u201012\u201000163"],"award-info":[{"award-number":["22\u201012\u201000163"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012190","name":"Ministry of Science and Higher Education of the Russian Federation","doi-asserted-by":"publisher","award":["0023\u20102019\u20100005"],"award-info":[{"award-number":["0023\u20102019\u20100005"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2023,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The chemical interaction of Sn with H\n                    <jats:sub>2<\/jats:sub>\n                    by X\u2010ray diffraction methods at pressures of 180\u2013210\u00a0GPa is studied. A previously unknown tetrahydride SnH\n                    <jats:sub>4<\/jats:sub>\n                    with a cubic structure (\n                    <jats:italic>fcc<\/jats:italic>\n                    ) exhibiting superconducting properties below\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>C<\/jats:sub>\n                    \u00a0= 72 K is obtained; the formation of a high molecular\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>m<\/jats:italic>\n                    \u2010SnH\n                    <jats:sub>14<\/jats:sub>\n                    superhydride and several lower hydrides,\n                    <jats:italic>fcc<\/jats:italic>\n                    SnH\n                    <jats:sub>2<\/jats:sub>\n                    , and\n                    <jats:italic>C<\/jats:italic>\n                    2\u2010Sn\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    , is also detected. The temperature dependence of critical current density\n                    <jats:italic>J<\/jats:italic>\n                    <jats:sub>C<\/jats:sub>\n                    (T) in SnH\n                    <jats:sub>4<\/jats:sub>\n                    yields the superconducting gap 2\u0394(0)\u00a0= 21.6 meV at 180\u00a0GPa. SnH\n                    <jats:sub>4<\/jats:sub>\n                    has unusual behavior in strong magnetic fields:\n                    <jats:italic>B,T<\/jats:italic>\n                    \u2010linear dependences of magnetoresistance and the upper critical magnetic field\n                    <jats:italic>B<\/jats:italic>\n                    <jats:sub>C2<\/jats:sub>\n                    (T) \u221d (\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>C<\/jats:sub>\n                    \u2013\n                    <jats:italic>T<\/jats:italic>\n                    ). The latter contradicts the Wertheimer\u2013Helfand\u2013Hohenberg model developed for conventional superconductors. Along with this, the temperature dependence of electrical resistance of\n                    <jats:italic>fcc<\/jats:italic>\n                    SnH\n                    <jats:sub>4<\/jats:sub>\n                    in non\u2010superconducting state exhibits a deviation from what is expected for phonon\u2010mediated scattering described by the Bloch\u2010Gr\u00fcneisen model and is beyond the framework of the Fermi liquid theory. Such anomalies occur for many superhydrides, making them much closer to cuprates than previously believed.\n                  <\/jats:p>","DOI":"10.1002\/advs.202303622","type":"journal-article","created":{"date-parts":[[2023,8,26]],"date-time":"2023-08-26T00:07:20Z","timestamp":1693008440000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Non\u2010Fermi\u2010Liquid Behavior of Superconducting SnH\n                    <sub>4<\/sub>"],"prefix":"10.1002","volume":"10","author":[{"given":"Ivan A.","family":"Troyan","sequence":"first","affiliation":[{"name":"Shubnikov Institute of Crystallography Federal Scientific Research Center Crystallography and Photonics Russian Academy of Sciences  59 Leninsky Prospekt Moscow 119333 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1374-9091","authenticated-orcid":false,"given":"Dmitrii V.","family":"Semenok","sequence":"additional","affiliation":[{"name":"Center for High Pressure Science and Technology Advanced Research (HPSTAR)  Beijing 100193 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anna G.","family":"Ivanova","sequence":"additional","affiliation":[{"name":"Shubnikov Institute of Crystallography Federal Scientific Research Center Crystallography and Photonics Russian Academy of Sciences  59 Leninsky Prospekt Moscow 119333 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey V.","family":"Sadakov","sequence":"additional","affiliation":[{"name":"V. L. Ginzburg Center for High\u2010Temperature Superconductivity and Quantum Materials P. N. Lebedev Physical Institute Russian Academy of Sciences  Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7534-5615","authenticated-orcid":false,"given":"Di","family":"Zhou","sequence":"additional","affiliation":[{"name":"Center for High Pressure Science and Technology Advanced Research (HPSTAR)  Beijing 100193 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander G.","family":"Kvashnin","sequence":"additional","affiliation":[{"name":"Skolkovo Institute of Science and Technology  Bolshoy Boulevard, 30\/1 Moscow 121205 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivan A.","family":"Kruglov","sequence":"additional","affiliation":[{"name":"Center for Fundamental and Applied Research Dukhov Research Institute of Automatics (VNIIA)  st. Sushchevskaya, 22 Moscow 127055 Russia"},{"name":"Laboratory of Computational Materials Discovery Moscow Institute of Physics and Technology  9 Institutsky Lane Dolgoprudny 141700 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleg A.","family":"Sobolevskiy","sequence":"additional","affiliation":[{"name":"V. L. Ginzburg Center for High\u2010Temperature Superconductivity and Quantum Materials P. N. Lebedev Physical Institute Russian Academy of Sciences  Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marianna V.","family":"Lyubutina","sequence":"additional","affiliation":[{"name":"Shubnikov Institute of Crystallography Federal Scientific Research Center Crystallography and Photonics Russian Academy of Sciences  59 Leninsky Prospekt Moscow 119333 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitry S.","family":"Perekalin","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences  28 Vavilova str. Moscow 119334 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Toni","family":"Helm","sequence":"additional","affiliation":[{"name":"Hochfeld\u2010Magnetlabor Dresden (HLD\u2010EMFL) and W\u00fcrzburg\u2010Dresden Cluster of Excellence Helmholtz\u2010Zentrum Dresden\u2010Rossendorf (HZDR)  01328 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stanley W.","family":"Tozer","sequence":"additional","affiliation":[{"name":"National High Magnetic Field Laboratory Florida State University  Tallahassee Florida 32310 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maxim","family":"Bykov","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Cologne  50939 Cologne Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander F.","family":"Goncharov","sequence":"additional","affiliation":[{"name":"Earth and Planets Laboratory Carnegie Institution for Science  5241 Broad Branch Road NW Washington DC 20015 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir M.","family":"Pudalov","sequence":"additional","affiliation":[{"name":"V. L. Ginzburg Center for High\u2010Temperature Superconductivity and Quantum Materials P. N. Lebedev Physical Institute Russian Academy of Sciences  Moscow 119991 Russia"},{"name":"HSE Tikhonov Moscow Institute of Electronics and Mathematics National Research University Higher School of Economics  20 Myasnitskaya ulitsa Moscow 101000 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Igor S.","family":"Lyubutin","sequence":"additional","affiliation":[{"name":"Shubnikov Institute of Crystallography Federal Scientific Research Center Crystallography and Photonics Russian Academy of Sciences  59 Leninsky Prospekt Moscow 119333 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,8,25]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14964"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1201-8"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.122.027001"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2019.10.005"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202006832"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-25372-2"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.127.117001"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.128.167001"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30454-w"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cossms.2020.100808"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b01353"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.3390\/cryst11121499"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nww029"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.103.065701"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0907729106"},{"key":"e_1_2_9_16_1","unstructured":"P. P.Kong A. P.Drozdov E.Eroke M. I.Eremets presented atBook of abstracts of AIRAPT 26 joint with ACHPR 8 & CHPC 19 Pressure\u2010induced superconductivity above 79 K in Si2H6 Beijing2017."},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.95.134506"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3505299"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp211051r"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0908342107"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.103.035131"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep16475"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.107.037002"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0056400"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtphys.2021.100596"},{"key":"e_1_2_9_26_1","unstructured":"C.Ritter J. Synthesis of stannane and deuterostannane. the US patent WO\/2012\/0216342012."},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1134\/S0021364017230011"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.84.140104"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep22873"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202200924"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.103.134505"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202204038"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2021.03.025"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-20103-5"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-26706-w"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42005-020-00505-z"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01341426"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.108.1175"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.147.295"},{"key":"e_1_2_9_40_1","unstructured":"I.Osmond J.Buhot presented atConference on Science at Extreme Conditions oral reports 2021."},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature07058"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature07676"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.73.094510"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.84.104502"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.101.104506"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.72.212509"},{"key":"e_1_2_9_47_1","volume-title":"Computational design of new superconducting materials and their targeted experimental synthesis Doctoral program in materials science and engineering thesis","author":"Semenok D.","year":"2022"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1088\/1367-2630\/ac8a0c"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.74.2800"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.87.087001"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8820"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.201700197"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2259"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.78.195308"},{"key":"e_1_2_9_55_1","first-page":"127","volume":"36","author":"DREIZIN Y. A.","year":"1973","journal-title":"Sov. Phys. JETP"},{"key":"e_1_2_9_56_1","first-page":"63","volume":"32","author":"Dykhne A. M.","year":"1971","journal-title":"Sov. Phys. JETP"},{"key":"e_1_2_9_57_1","first-page":"864","volume":"38","author":"Gorskii P. V.","year":"2004","journal-title":"Physica i Technika polurpovodnikov"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.100.155139"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41567-018-0334-2"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41567-022-01763-0"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-conmatphys-031119-050558"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0091446"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.19003060312"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.19003081102"},{"key":"e_1_2_9_65_1","first-page":"768","volume":"81","author":"Al'tshuler B. L.","year":"1981","journal-title":"Zh. Eksp. Teor. Fiz."},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.100.056802"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-3093(70)90055-4"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.46.565"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.13.3203"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-25687-0"},{"key":"e_1_2_9_71_1","unstructured":"A. P.Drozdov M. I.Eremets I. A.Troyan arXiv:1508.06224 2015."},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38254-6"},{"key":"e_1_2_9_73_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41567-022-01513-2"},{"key":"e_1_2_9_74_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.physc.2015.02.047"},{"key":"e_1_2_9_75_1","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.78.17"},{"key":"e_1_2_9_76_1","first-page":"696","volume":"11","author":"Eliashberg G. M.","year":"1959","journal-title":"Sov. Phys. JETP"},{"key":"e_1_2_9_77_1","first-page":"996","volume":"34","author":"Migdal A. B.","year":"1958","journal-title":"Sov. Phys. JETP"},{"key":"e_1_2_9_78_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.106.054518"},{"key":"e_1_2_9_79_1","doi-asserted-by":"publisher","DOI":"10.1070\/PU1992v035n05ABEH002235"},{"key":"e_1_2_9_80_1","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1591\/ab6770"},{"key":"e_1_2_9_81_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6668\/abb11a"},{"key":"e_1_2_9_82_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14154322"},{"key":"e_1_2_9_83_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rinp.2020.102993"},{"key":"e_1_2_9_84_1","unstructured":"M. A.Kuzovnikov presented atELBRUS2021 V(P) equations of state of novel lanthanum and yttrium superhydrides 2021."}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202303622","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202303622","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T23:14:15Z","timestamp":1759792455000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202303622"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,25]]},"references-count":84,"journal-issue":{"issue":"30","published-print":{"date-parts":[[2023,10]]}},"alternative-id":["10.1002\/advs.202303622"],"URL":"https:\/\/doi.org\/10.1002\/advs.202303622","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,25]]},"assertion":[{"value":"2023-06-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-08-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2303622"}}