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However, its photocatalytic ORR activity toward H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    generation is still unsatisfied for practical application. Herein, 3\u2010hydroxythiophenol\u2010formaldehyde (3\u2010HTPF) resin microspheres synthesized through polycondensation reaction between 3\u2010HTP and formaldehyde at room temperature and subsequent hydrothermal treatment exhibit enhanced photocatalytic ORR activity is reported. The experimental results show that the partial substitution of hydroxy group (\u2500OH) by sulfhydryl one (\u2500SH) through using 3\u2010HTP to replace resorcinol could slow the rates of nucleation and growth of the resin particles and lead to strongly\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010stacked architecture in 3\u2010HTPF. The introduction of \u2500SH group can also improve adsorption ability of 3\u2010HTPF to O\n                    <jats:sub>2<\/jats:sub>\n                    molecules and enhance ORR catalytic activity of the photocatalysts. Stronger built\u2010in electric field, better adsorption ability to O\n                    <jats:sub>2<\/jats:sub>\n                    molecules, and increased surface catalytic activity collectively boost photocatalytic activity of 3\u2010HTPF microspheres. As a result, H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production rate of 2010\u00a0\u00b5\n                    <jats:sc>m<\/jats:sc>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    is achieved over 3\u2010HTPF microspheres at 273\u00a0K, which is 3.4 times larger than that obtained using RF submicrospheres (591\u00a0\u00b5\n                    <jats:sc>m<\/jats:sc>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). The rational substituent group modulation provides a new strategy for designing polymeric photocatalysts at the molecular level toward high\u2010efficiency artificial photosynthesis.\n                  <\/jats:p>","DOI":"10.1002\/advs.202304948","type":"journal-article","created":{"date-parts":[[2023,12,10]],"date-time":"2023-12-10T21:45:18Z","timestamp":1702244718000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["3\u2010Hydroxythiophenol\u2010Formaldehyde Resin Microspheres Modulated by Sulfhydryl Groups for Highly Efficient Photocatalytic Synthesis of H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"11","author":[{"given":"Yulu","family":"Xu","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xia","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Life Science Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuyuan","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijie","family":"Lin","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Wang","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Faliang","family":"Gou","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaogang","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute of Materials Science and Devices Suzhou University of Science and Technology  Suzhou 215011 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiwei","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Syracuse University  Syracuse NY 13244 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6958-150X","authenticated-orcid":false,"given":"De\u2010Kun","family":"Ma","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process Shaoxing University  Shaoxing 312000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,10]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0017-x"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01218-7"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00605-1"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-14240-9"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911609"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.04.024"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01925A"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2022.01.058"},{"key":"e_1_2_8_9_1","volume":"39","author":"Zan Z. 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