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The electronic structure of [(ADC)SnP]<jats:sub>2<\/jats:sub> is analyzed by quantum\u2010chemical calculations. At room temperature, [(ADC)SnP]<jats:sub>2<\/jats:sub> reversibly binds with CO<jats:sub>2<\/jats:sub> and forms [(ADC)<jats:sub>2<\/jats:sub>{SnOC(O)P}SnP]. [(ADC)SnP]<jats:sub>2<\/jats:sub> enables catalytic hydroboration of CO<jats:sub>2<\/jats:sub> and reacts with elemental selenium and Fe<jats:sub>2<\/jats:sub>(CO)<jats:sub>9<\/jats:sub> to afford [(ADC)<jats:sub>2<\/jats:sub>{Sn(Se)P<jats:sub>2<\/jats:sub>}SnSe] and [(ADC)Sn{Fe(CO)<jats:sub>4<\/jats:sub>}P]<jats:sub>2<\/jats:sub>, respectively. All compounds are characterized by multinuclear NMR spectroscopy and their solid\u2010state molecular structures are determined by single\u2010crystal X\u2010ray diffraction.<\/jats:p>","DOI":"10.1002\/advs.202305545","type":"journal-article","created":{"date-parts":[[2023,11,29]],"date-time":"2023-11-29T02:40:27Z","timestamp":1701225627000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Isolation of an Anionic Dicarbene Embedded Sn<sub>2<\/sub>P<sub>2<\/sub> Cluster and Reversible CO<sub>2<\/sub> Uptake"],"prefix":"10.1002","volume":"11","author":[{"given":"Falk","family":"Ebeler","sequence":"first","affiliation":[{"name":"Molecular Inorganic Chemistry and Catalysis Inorganic and Structural Chemistry Center for Molecular Materials Faculty of Chemistry Universit\u00e4t Bielefeld  Universit\u00e4tsstrasse 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yury 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