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However, the propensity for C\u2500H bonds in the desired products to cleave more easily than those in methane molecules results in a continuous dehydrogenation process, inevitably leading to methanol peroxidation. Consequently, inhibiting methanol peroxidation is perceived as one of the most formidable challenges in the field of direct conversion of methane to methanol. This review offers a thorough overview of the typical mechanisms involved radical mechanism and active site mechanism and the regulatory methods employed to inhibit product peroxidation in methane photooxidation. Additionally, several perspectives on the future research direction of this crucial field are proposed.<\/jats:p>","DOI":"10.1002\/advs.202306891","type":"journal-article","created":{"date-parts":[[2024,1,18]],"date-time":"2024-01-18T02:55:11Z","timestamp":1705546511000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Product Peroxidation Inhibition in Methane Photooxidation into Methanol"],"prefix":"10.1002","volume":"11","author":[{"given":"Yuehan","family":"Cao","sequence":"first","affiliation":[{"name":"National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum University  Chengdu 610500 China"},{"name":"School of New Energy and Materials Southwest Petroleum University  Chengdu 610500 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zeai","family":"Huang","sequence":"additional","affiliation":[{"name":"School of New Energy and Materials Southwest Petroleum University  Chengdu 610500 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunqiu","family":"Han","sequence":"additional","affiliation":[{"name":"School of New Energy and Materials Southwest Petroleum University  Chengdu 610500 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9995-0652","authenticated-orcid":false,"given":"Ying","family":"Zhou","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum University  Chengdu 610500 China"},{"name":"School of New Energy and Materials Southwest Petroleum University  Chengdu 610500 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,17]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202001946"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050362v"},{"key":"e_1_2_7_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803393"},{"key":"e_1_2_7_1_4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00745"},{"key":"e_1_2_7_1_5","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE00604F"},{"key":"e_1_2_7_1_6","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60120j"},{"key":"e_1_2_7_1_7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702550"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.1c05152"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00194"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00439"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202300122"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202301073"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01279-1"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c13661"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108069"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2023.05.007"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214042"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature24640"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aan6515"},{"key":"e_1_2_7_6_3","doi-asserted-by":"publisher","DOI":"10.1126\/science.aam9035"},{"key":"e_1_2_7_6_4","unstructured":"d) BP BP Statistical Review of World Energy2022 2022."},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-0564(08)60455-1"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(00)00503-4"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(98)00236-3"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.1999.2732"},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","DOI":"10.3866\/PKU.WHXB202303029","volume":"40","author":"Cao Y.","year":"2024","journal-title":"Acta Phys. \u2010Chim. 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