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However, CO can be easily generated and poison the catalytic system under such high temperature. Therefore, it is highly desirable to develop the efficient catalytic systems for H<jats:sub>2<\/jats:sub> production from methanol at room temperature, even at sub\u2010zero temperatures. Herein, carbon nanotube\u2010supported Pt nanocomposites are designed and synthesized as high\u2010performance nano\u2010catalysts, via stabilization of Pt nanoparticles onto carbon nanotube (CNT), for H<jats:sub>2<\/jats:sub> production upon methanol dehydrogenation at sub\u2010zero temperatures. Therein, the optimal Pt\/CNT nanocomposite presents the superior catalytic performance in H<jats:sub>2<\/jats:sub> production upon methanol dehydrogenation at the expense of B<jats:sub>2<\/jats:sub>(OH)<jats:sub>4<\/jats:sub>, with the TOF of 299.51\u00a0min<jats:sup>\u20101<\/jats:sup>30 <jats:sup>o<\/jats:sup>C. Compared with other common carriers, Pt\/CNT exhibited the highest catalytic performance in H<jats:sub>2<\/jats:sub> production, emphasizing the critical role of CNT in methanol dehydrogenation. The confinement of Pt nanoparticles by CNTs is conducive to inhibiting the aggregation of Pt nanoparticles, thereby significantly increasing its catalytic performance and stability. The kinetic study, detailed mechanistic insights, and density functional theory (DFT) calculation confirm that the breaking of O\u2500H bond of CH<jats:sub>3<\/jats:sub>OH is the rate\u2010controlling step for methanol dehydrogenation, and both H atoms of H<jats:sub>2<\/jats:sub> are supplied by methanol. Interestingly, H<jats:sub>2<\/jats:sub> is also successfully produced from methanol dehydrogenation at \u221210\u00a0\u00b0C, which absolutely solves the freezing problem in the H<jats:sub>2<\/jats:sub> evolution upon water\u2010splitting reaction.<\/jats:p>","DOI":"10.1002\/advs.202306893","type":"journal-article","created":{"date-parts":[[2024,1,16]],"date-time":"2024-01-16T02:52:02Z","timestamp":1705373522000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Spatial Confinement of Pt Nanoparticles in Carbon Nanotubes for Efficient and Selective H<sub>2<\/sub> Evolution from Methanol"],"prefix":"10.1002","volume":"11","author":[{"given":"Xiaotao","family":"Jin","sequence":"first","affiliation":[{"name":"Engineering Research Center of Eco\u2010environment in Three Gorges Reservoir Region College of Materials and Chemical Engineering China Three Gorges University  Yichang Hubei 443002 P. R. 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