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MXene Ti3C2Tx is also a hydrophilic layered material composed by 2D sheets but so far pressure\u2010induced swelling is reported for this material only under conditions of shear stress at MPa pressures. Here, high\u2010pressure experiments are performed with MXenes prepared by two methods known to provide \u201cclay\u2010like\u201d materials. MXene synthesized by etching MAX phase with HCl+LiF demonstrates the effect of pressure\u2010induced swelling at 0.2\u00a0GPa with the insertion of additional water layer. The transition is incomplete with two swollen phases (ambient with d(001) = 16.7\u00c5 and pressure\u2010induced with d(001) = 19.2\u00c5 at 0.2\u00a0GPa) co\u2010existing up to the pressure point of water solidification. Therefore, the swelling transition corresponds to change from two\u2010layer water intercalation (2L\u2010phase) to a never previously observed three\u2010layer water intercalation (3L\u2010phase) of MXene. Experiments with MXene prepared by LiCl+HF etching have not revealed pressure\u2010induced swelling in liquid water. Both MXenes also show no anomalous compressibility in liquid methanol. The presence of pressure\u2010induced swelling only in one of the MXenes indicates that the HCl+LiF synthesis method is likely to result in higher abundance of hydrophilic functional groups terminating 2D titanium carbide.<\/jats:p>","DOI":"10.1002\/advs.202307067","type":"journal-article","created":{"date-parts":[[2023,12,14]],"date-time":"2023-12-14T09:37:31Z","timestamp":1702546651000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Swelling of Ti<sub>3<\/sub>C<sub>2<\/sub>T<sub>x<\/sub> MXene in Water and Methanol at Extreme Pressure Conditions"],"prefix":"10.1002","volume":"11","author":[{"given":"Artem","family":"Iakunkov","sequence":"first","affiliation":[{"name":"Department of Physics Ume\u00e5 University  Ume\u00e5 SE\u2010901 87 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ulrich","family":"Lienert","sequence":"additional","affiliation":[{"name":"DESY Photon Science  22607 Hamburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhua","family":"Sun","sequence":"additional","affiliation":[{"name":"Department of Industrial and Materials Science Chalmers University of Technology  G\u00f6teborg SE\u2010412 96 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandr V.","family":"Talyzin","sequence":"additional","affiliation":[{"name":"Department of Physics Ume\u00e5 University  Ume\u00e5 SE\u2010901 87 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,14]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b06394"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1849"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1346\/CCMN.1955.0040132"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19345100102"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR04931J"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpcs.2006.01.031"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b04546"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13970"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201102306"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3NR04631A"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17373-4"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2017.21"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.105"},{"key":"e_1_2_7_6_2","first-page":"9","volume":"29","author":"Zhang C. 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