{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:04:49Z","timestamp":1789085089580,"version":"build-2803163510"},"reference-count":53,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2024,6,18]],"date-time":"2024-06-18T00:00:00Z","timestamp":1718668800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100020595","name":"National Science and Technology Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100020595","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2024,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A cost\u2010effective chemical prelithiation solution, which consists of Li\n                    <jats:sup>+<\/jats:sup>\n                    , polyaromatic hydrocarbon (PAH), and solvent, is developed for a model hard carbon (HC) electrode. Naphthalene and methyl\u2010substituted naphthalene PAHs, namely 2\u2010methylnaphthalene and 1\u2010methylnaphthalene, are first compared. Grafting an electron\u2010donating methyl group onto the benzene ring can decrease electron affinity and thus reduce the redox potential, which is validated by density functional theory calculations. Ethylene glycol dimethyl ether (G1), diethylene glycol dimethyl ether, and triethylene glycol dimethyl ether solvents are then compared. The G1 solution has the highest conductivity and least steric hindrance, and thus the 1\u2010methylnaphthalene\/G1 solution shows superior prelithiation capability. In addition, the effects of the interaction time between Li\n                    <jats:sup>+<\/jats:sup>\n                    and 1\u2010methylnaphthalene in G1 solvent on the electrochemical properties of a prelithiated HC electrode are investigated. Nuclear magnetic resonance data confirm that 10\u2010h aging is needed to achieve a stable solution coordination state and thus optimal prelithiation efficacy. It is also found that appropriate prelithiation creates a more Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010conducing and robust solid\u2010electrolyte interphase, improving the rate capability and cycling stability of the HC electrode.\n                  <\/jats:p>","DOI":"10.1002\/advs.202309155","type":"journal-article","created":{"date-parts":[[2024,6,19]],"date-time":"2024-06-19T01:40:40Z","timestamp":1718761240000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Engineering of Aromatic Naphthalene and Solvent Molecules to Optimize Chemical Prelithiation for Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9783-3097","authenticated-orcid":false,"given":"Jagabandhu","family":"Patra","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering National Yang Ming Chiao Tung University  1001 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