{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T04:04:42Z","timestamp":1791086682844,"version":"4.1.0"},"reference-count":36,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2024,3,14]],"date-time":"2024-03-14T00:00:00Z","timestamp":1710374400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22209039"],"award-info":[{"award-number":["22209039"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2024,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Designing high efficiency platinum (Pt)\u2010based catalysts for methanol oxidation reaction (MOR) with high \u201cnon\u2010CO\u201d pathway selectivity is strongly desired and remains a grand challenge. Herein, PtRuNiCoFeGaPbW HEA ultrathin nanowires (HEA\u20108 UNWs) are synthesized, featuring unique cascaded\n                    <jats:italic>p<\/jats:italic>\n                    \u2013\n                    <jats:italic>d<\/jats:italic>\n                    orbital hybridization interaction by inducing dual\n                    <jats:italic>p<\/jats:italic>\n                    \u2010block metals (Ga and Pb). In comparison with Pt\/C, HEA\u20108 UNWs exhibit 15.0\u2010 and 4.2\u2010times promotion of specific and mass activity for MOR. More importantly, electrochemical in situ FITR spectroscopy reveals that the production\/adsorption of CO (CO\n                    <jats:sup>*<\/jats:sup>\n                    ) intermediate is effectively avoided on HEA\u20108 UNWs, leading to the complete \u201cnon\u2010CO\u201d pathway for MOR. Theoretical calculations demonstrate the optimized electronic structure of HEA\u20108 UNWs can facilitates a lower energy barrier for the \u201cnon\u2010CO\u201d pathway in the MOR.\n                  <\/jats:p>","DOI":"10.1002\/advs.202309813","type":"journal-article","created":{"date-parts":[[2024,3,14]],"date-time":"2024-03-14T05:24:36Z","timestamp":1710393876000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Cascaded\n                    <i>p\u2013d<\/i>\n                    Orbital Hybridization Interaction in Ultrathin High\u2010Entropy Alloy Nanowires Boosts Complete Non\u2010CO Pathway of Methanol Oxidation Reaction"],"prefix":"10.1002","volume":"11","author":[{"given":"Yipin","family":"Lv","sequence":"first","affiliation":[{"name":"College of sciences Henan Agricultural University  Zhengzhou Henan 450000 P. R. 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