{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T21:22:24Z","timestamp":1792790544393,"version":"4.5.0"},"reference-count":52,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2024,3,27]],"date-time":"2024-03-27T00:00:00Z","timestamp":1711497600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373238"],"award-info":[{"award-number":["52373238"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52003225"],"award-info":[{"award-number":["52003225"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2024,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The electroreduction of carbon dioxide (CO<jats:sub>2<\/jats:sub>) to multi\u2010carbon (C<jats:sub>2+<\/jats:sub>) compounds offers a viable approach for the up\u2010conversion of greenhouse gases into valuable fuels and feedstocks. Nevertheless, current industrial applications face limitations due to unsatisfactory conversion efficiency and high overpotential. Herein, a facile and scalable plasma fluorination method is reported. Concurrently, self\u2010evolution during CO<jats:sub>2<\/jats:sub> electroreduction is employed to control the active sites of Cu catalysts. The copper catalyst modified with fluorine exhibits an impressive C<jats:sub>2+<\/jats:sub> Faradaic efficiency (FE) of 81.8% at a low potential of \u22120.56\u00a0V (vs a reversible hydrogen electrode) in an alkaline flow cell. The presence of modified fluorine leads to the exposure and stabilization of high\u2010activity Cu<jats:sup>+<\/jats:sup> species, enhancing the adsorption of *CO intermediates and the generation of *CHO, facilitating the subsequent dimerization. This results in a notably improved conversion efficiency of 13.1% and a significant reduction in the overpotential (\u2248100\u00a0mV) for the C<jats:sub>2+<\/jats:sub> products. Furthermore, a superior C<jats:sub>2+<\/jats:sub> FE of 81.6% at 250\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup>, coupled with an energy efficiency of 31.0%, can be achieved in a two\u2010electrode membrane electrode assembly electrolyzer utilizing the fluorine\u2010modified copper catalyst. The strategy provides novel insights into the controllable electronic modification and surface reconstruction of electrocatalysts with practical potential.<\/jats:p>","DOI":"10.1002\/advs.202309963","type":"journal-article","created":{"date-parts":[[2024,3,28]],"date-time":"2024-03-28T01:41:37Z","timestamp":1711590097000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Enhanced CO<sub>2<\/sub> Electroreduction to Multi\u2010Carbon Products on Copper via Plasma Fluorination"],"prefix":"10.1002","volume":"11","author":[{"given":"Ziqian","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Zhejiang University  Hangzhou 310027 China"},{"name":"Research Center for Industries of the Future (RCIF) School of Engineering and Key Laboratory of 3D Micro\/Nano Fabrication and Characterization of Zhejiang Province School of Engineering Westlake University  Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaosong","family":"Hu","sequence":"additional","affiliation":[{"name":"Research Center for Industries of the Future (RCIF) School of Engineering and Key Laboratory of 3D Micro\/Nano Fabrication and Characterization of Zhejiang Province School of Engineering Westlake University  Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiye","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Zhejiang University  Hangzhou 310027 China"},{"name":"Research Center for Industries of the Future (RCIF) School of Engineering and Key Laboratory of 3D Micro\/Nano Fabrication and Characterization of Zhejiang Province School of Engineering Westlake University  Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haijiao","family":"Xie","sequence":"additional","affiliation":[{"name":"Hangzhou Yanqu Information Technology Co., Ltd  Hangzhou 310003 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3185-575X","authenticated-orcid":false,"given":"Liaoyong","family":"Wen","sequence":"additional","affiliation":[{"name":"Research Center for Industries of the Future (RCIF) School of Engineering and Key Laboratory of 3D Micro\/Nano Fabrication and Characterization of Zhejiang Province School of Engineering Westlake University  Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,27]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4002758"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.2c00922"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0450-y"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1088\/1674-4926\/44\/3\/031701"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2017.10.014"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00230E"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-0450-0"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201700736"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0084-7"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2242-8"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36926-x"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0018-9"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02399"},{"key":"e_1_2_7_6_3","doi-asserted-by":"publisher","DOI":"10.1038\/nature19060"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-019-0551-6"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b12381"},{"key":"e_1_2_7_7_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0383-7"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aay4217"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200039"},{"key":"e_1_2_7_8_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-022-01092-9"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0594-9"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11599-7"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12123"},{"key":"e_1_2_7_9_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2023.101256"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0092-x"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.07.009"},{"key":"e_1_2_7_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102657"},{"key":"e_1_2_7_10_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116706"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16998-9"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1116\/1.569958"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705850"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1088\/1674-4926\/42\/5\/052701"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19236-4"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(02)00951-8"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301127"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805256"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19135-8"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00973-9"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-00958-9"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1088\/1674-4926\/42\/7\/072701"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00848E"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00849A"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b03910"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13384"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0607-8"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2008.09.064"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06820"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/376238a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203896"},{"key":"e_1_2_7_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112116"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01562"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtphys.2023.101045"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202309963","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T11:46:19Z","timestamp":1759751179000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202309963"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,3,27]]},"references-count":52,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2024,6]]}},"alternative-id":["10.1002\/advs.202309963"],"URL":"https:\/\/doi.org\/10.1002\/advs.202309963","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,3,27]]},"assertion":[{"value":"2023-12-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-03-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2309963"}}