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In this report, a polycaprolactone\u2010based poly(urethane\u2010urea) elastomer is presented with excellent mechanical properties by optimizing the arrangement of hard segment clusters. It is found that long alkyl chains of the chain extenders lead to small and evenly distributed hard segment clusters, which is beneficial for improving mechanical properties. Together with the multiple hydrogen bond structure and stress\u2010induced crystallization, the obtained elastomer exhibits a high strength of 63.3\u00a0MPa, an excellent toughness of 431\u00a0MJ\u00a0m\n                    <jats:sup>\u22123<\/jats:sup>\n                    and an outstanding fracture energy of 489\u00a0kJ\u00a0m\n                    <jats:sup>\u22122<\/jats:sup>\n                    , while maintaining good recyclability and degradability. It is believed that the obtained elastomer holds great promise in various application fields and it contributes to the development of a sustainable society.\n                  <\/jats:p>","DOI":"10.1002\/advs.202400255","type":"journal-article","created":{"date-parts":[[2024,4,11]],"date-time":"2024-04-11T09:43:35Z","timestamp":1712828615000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":100,"title":["Regulation of Hard Segment Cluster Structures for High\u2010performance Poly(urethane\u2010urea) Elastomers"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5614-5231","authenticated-orcid":false,"given":"Jianliang","family":"Qin","sequence":"first","affiliation":[{"name":"School of Science and Engineering The Chinese University of Hong Kong, Shenzhen  Shenzhen 518172 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