{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T22:09:48Z","timestamp":1792793388313,"version":"4.5.0"},"reference-count":55,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["91961201"],"award-info":[{"award-number":["91961201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2024,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Ligand\u2010protected heterometallic nanoclusters in contrast to homo\u2010metal counterparts show more broad applications due to the synergistic effect of hetero\u2010metals but their controllable syntheses remain a challenge. Among heterometallic nanoclusters, monovalent Ag\u2010Cu compounds are rarely explored due to much difference of Ag(I) and Cu(I) such as atom radius, coordination habits, and redox potential. Encouraged by copper\u2010catalyzed alkyne\u2010azide cycloaddition (CuAAC) reaction, comproportionation reaction of Cu(II)X<jats:sub>2<\/jats:sub> and Cu(0) in the presence of (PhC\u2261CAg)<jats:sub>n<\/jats:sub> complex and molybdate generated a core\u2010shell peanut\u2010shaped 66\u2010nuclear Ag(I)\u2010Cu(I) heterometallic nanocluster, [(Mo<jats:sub>4<\/jats:sub>O<jats:sub>16<\/jats:sub>)<jats:sub>2<\/jats:sub>@Cu<jats:sub>12<\/jats:sub>Ag<jats:sub>54<\/jats:sub>(PhC\u2261C)<jats:sub>50<\/jats:sub>] (referred to as <jats:bold>Ag<jats:sub>54<\/jats:sub>Cu<jats:sub>12<\/jats:sub><\/jats:bold>). The structure and composition of Ag\u2010Cu heterometallic nanocluster are fully characterized. X\u2010ray single crystal diffraction reveals that <jats:bold>Ag<jats:sub>54<\/jats:sub>Cu<jats:sub>12<\/jats:sub><\/jats:bold> has a peanut\u2010shaped silver(I)\/copper(I) heterometallic nanocage protected by fifty phenylacetylene ligands in <jats:italic>\u00b5<\/jats:italic><jats:sub>3<\/jats:sub>\u2013modes and encapsulated two mutually twisted tetramolybdates. Heterometallic nanocage contains a 54\u2010Ag\u2010atom outer ellipsoid silver cage decorated by 12 copper inside wall. Nanosized <jats:bold>Ag<jats:sub>54<\/jats:sub>Cu<jats:sub>12<\/jats:sub><\/jats:bold> is a <jats:italic>n<\/jats:italic>\u2010type narrow\u2010band\u2010gap semiconductor with a good photocurrent response. Preliminary experiments demonstrates that <jats:bold>Ag<jats:sub>54<\/jats:sub>Cu<jats:sub>12<\/jats:sub><\/jats:bold> itself and activated carbon supported <jats:bold>Ag<jats:sub>54<\/jats:sub>Cu<jats:sub>12<\/jats:sub>\/C<\/jats:bold> are effective catalysts for 1,3\u2010dipole cycloaddition between alkynes and azides at ambient conditions. The work provides not only a new synthetic route toward Ag(I)\u2010Cu(I) nanoclusters but also an important heterometallic intermediate in CuAAC catalytic reaction.<\/jats:p>","DOI":"10.1002\/advs.202400377","type":"journal-article","created":{"date-parts":[[2024,4,2]],"date-time":"2024-04-02T01:39:36Z","timestamp":1712021976000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["A 66\u2010Nuclear All\u2010Alkynyl Protected Peanut\u2010Shaped Silver(I)\/Copper(I) Heterometallic Nanocluster: Intermediate in Copper\u2010Catalyzed Alkyne\u2010Azide Cycloaddition"],"prefix":"10.1002","volume":"11","author":[{"given":"Jin\u2010Ping","family":"Gao","sequence":"first","affiliation":[{"name":"School of Chemistry &amp; Material Science Shanxi Normal University  Taiyuan 030006 P. R. 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