{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T01:58:25Z","timestamp":1791943105928,"version":"4.3.4"},"reference-count":43,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2024,6,12]],"date-time":"2024-06-12T00:00:00Z","timestamp":1718150400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE\u2010AC02\u201006CH11357"],"award-info":[{"award-number":["DE\u2010AC02\u201006CH11357"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017535","name":"Energy Frontier Research Centers","doi-asserted-by":"publisher","award":["DE\u2010SC0021314"],"award-info":[{"award-number":["DE\u2010SC0021314"]}],"id":[{"id":"10.13039\/100017535","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2024,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Singlet\u2010to\u2010triplet intersystem crossing (ISC) in organic molecules is intimately connected with their geometries: by modifying the molecular shape, symmetry selection rules pertaining to spin\u2010orbit coupling can be partially relieved, leading to extra matrix elements for increased ISC. As an analog to this molecular design concept, the study finds that the lattice symmetry of supramolecular polymers also defines their triplet formation efficiencies. A supramolecular polymer self\u2010assembled from weakly interacting molecules is considered. Its 2D oblique unit cell effectively renders it as a coplanar array of 1D molecular columns weakly bound to each other. Using momentum\u2010resolved photoluminescence imaging in combination with Monte Carlo simulations, the study found that photogenerated charge carriers in the supramolecular polymer predominantly recombine as spin\u2010uncorrelated carrier pairs through inter\u2010column charge transfer states. This lattice\u2010defined recombination pathway leads to a substantial triplet formation efficiency (\u224860%) in the supramolecular polymer. These findings suggest that lattice symmetry of micro\u2010\/macroscopic structures relying on intermolecular interactions can be strategized for controlled triplet formation.<\/jats:p>","DOI":"10.1002\/advs.202402932","type":"journal-article","created":{"date-parts":[[2024,6,12]],"date-time":"2024-06-12T08:34:14Z","timestamp":1718181254000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Lattice Symmetry\u2010Guided Charge Transport in 2D Supramolecular Polymers Promotes Triplet Formation"],"prefix":"10.1002","volume":"11","author":[{"given":"Ruggero","family":"Emmanuele","sequence":"first","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroaki","family":"Sai","sequence":"additional","affiliation":[{"name":"Simpson Querrey Institute for BioNanotechnology Northwestern University  Chicago IL 60611 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Shiang","family":"Chen","sequence":"additional","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"},{"name":"Simpson Querrey Institute for BioNanotechnology Northwestern University  Chicago IL 60611 USA"},{"name":"Center for Molecular Quantum Transduction Northwestern University  Evanston IL 60208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Darien J.","family":"Morrow","sequence":"additional","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luka","family":"\u0110or\u0111evi\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry Northwestern University  Evanston IL 60208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David J.","family":"Gosztola","sequence":"additional","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saw Wai","family":"Hla","sequence":"additional","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"},{"name":"Nanoscale and Quantum Phenomena Institute and Department of Physics and Astronomy Ohio University  Athens OH 45701 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samuel I.","family":"Stupp","sequence":"additional","affiliation":[{"name":"Simpson Querrey Institute for BioNanotechnology Northwestern University  Chicago IL 60611 USA"},{"name":"Department of Chemistry Northwestern University  Evanston IL 60208 USA"},{"name":"Department of Materials Science and Engineering Northwestern University  Evanston IL 60208 USA"},{"name":"Department of Medicine Northwestern University  Chicago IL 60611 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3163-1249","authenticated-orcid":false,"given":"Xuedan","family":"Ma","sequence":"additional","affiliation":[{"name":"Center for Nanoscale Materials Argonne National Laboratory  Lemont IL 60439 USA"},{"name":"Center for Molecular Quantum Transduction Northwestern University  Evanston IL 60208 USA"},{"name":"Consortium for Advanced Science and Engineering University of Chicago  Chicago IL 60637 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-04636-x"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05342-4"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-021-00904-w"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-018-0835-2"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-021-00763-5"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60240a004"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00060"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c9pp00399a"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp800561g"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(75)85698-3"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp075248q"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo5010235"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2075"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-022-01289-9"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201907247"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990517)38:10<1393::AID-ANIE1393>3.0.CO;2-H"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0642360"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1205962"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0505645102"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10027"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c05024"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12641"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05673"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2013.20"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11225-6"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1364\/JOSAB.21.001210"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200800451"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.09.026"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.102.035437"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3329"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.120.745"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.58.856"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature12339"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202102354"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c04091"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/a902356i"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2SC21178E"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c00106"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201600300"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC01574C"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.07.010"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803102"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.53.1391"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202402932","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202402932","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:24:10Z","timestamp":1760405050000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202402932"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,6,12]]},"references-count":43,"journal-issue":{"issue":"30","published-print":{"date-parts":[[2024,8]]}},"alternative-id":["10.1002\/advs.202402932"],"URL":"https:\/\/doi.org\/10.1002\/advs.202402932","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,12]]},"assertion":[{"value":"2024-03-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-06-12","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2402932"}}