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However, if masks are not sterilized, changing them too frequently can actually increase the risk of cross\u2010contamination. Herein, the construction of an antipathogen photocatalytic mask with carbon vacancy\u2010modified carbon nitride nanosheets (g\u2010C<jats:sub>3<\/jats:sub>N<jats:sub>4<\/jats:sub>\u2010V<jats:sub>C<\/jats:sub> Ns) coated on the non\u2010woven fabrics of the out layer of the mask, offering effective and long\u2010term protection against damaging pathogens when exposed to light is reported. The introduced carbon vacancies are found capable of creating energy\u2010disordered sites and inducing energetic electric force to overcome the Coulomb interactions between electron\u2010hole pairs, thus promoting the electron\u2010hole separation to achieve a high generation of reactive oxygen species (ROS). Thanks to its high activity in generating ROS upon exposure to light, the as\u2010prepared photocatalytic mask shows high pathogen sterilization performance. This, in turn, prolongs the mask's protective lifetime, decreases the need for regular replacement, and decreases medical waste production. The work demonstrated here opens new viewpoints in designing pathogens biocidal protective devices for health protection, offering significant promise in specific environment self\u2010protection.<\/jats:p>","DOI":"10.1002\/advs.202403098","type":"journal-article","created":{"date-parts":[[2024,6,20]],"date-time":"2024-06-20T02:35:59Z","timestamp":1718850959000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Bioprotective Respirator Assembled by Defective Carbon Nitride for Long\u2010Term Light Triggered Health Protection"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7983-7246","authenticated-orcid":false,"given":"Zhenxing","family":"Zeng","sequence":"first","affiliation":[{"name":"College of Environmental Sciences Sichuan Agricultural University  Chengdu 611130 P. R. 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