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However, addressing the stability of Zn plating\/stripping at high current densities and areal capacities by this method is still a challenge, especially in capacitors known for high power and long life. Herein, an organic heterocyclic compound of 1, 4, 7, 10\u2010tetraazacyclododecane (TC) containing four symmetrically distributed N atoms is employed as ZS additive, expanding the life of Zn anodes from \u2248\u00a030\u00a0h to 1000 and 240\u00a0h at deep plating\/stripping conditions of 10 and 20\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup>\/mAh\u00a0cm<jats:sup>\u22122<\/jats:sup>, respectively; the cumulative capacity is as high as 5.0\u00a0Ah\u00a0cm<jats:sup>\u22122<\/jats:sup> with 99% Coulombic efficiency, far exceeding reported additives. TC with higher binding energies than H<jats:sub>2<\/jats:sub>O for Zn species tends to adsorb to Zn (002) in a lying manner and participate in the solvation shell of Zn<jats:sup>2+<\/jats:sup>, thus avoiding Zn dendrites and side\u2010reaction damage, especially at high current densities. The TC\u2010endowed Zn anode's stability under such extreme conditions is verified in Zn\u2010ion capacitors (i.e., &gt;\u00a094.6% capacity retention after 28\u00a0000 cycles), providing new insights into the development of high\u2010power Zn\u2010based energy storage devices.<\/jats:p>","DOI":"10.1002\/advs.202404323","type":"journal-article","created":{"date-parts":[[2024,6,25]],"date-time":"2024-06-25T15:43:46Z","timestamp":1719330226000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Easy\u2010to\u2010Lay Poly\u2010N Heterocyclic Additives Enable Long\u2010Term Stabilization of Zinc\u2010Ion Capacitor Anodes under Deep Plating\/Stripping"],"prefix":"10.1002","volume":"11","author":[{"given":"Yongfeng","family":"Bu","sequence":"first","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qin","family":"Kang","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaomin","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuman","family":"Li","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shihao","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute for Energy Research Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengda","family":"Tang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology, School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Pan","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology, School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyu","family":"Liang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Manufacturing and Modern Equipment Technology, School of Mechanical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,25]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.103085"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202311680"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300630"},{"key":"e_1_2_8_4_1","volume":"6","author":"Wang Q.","year":"2020","journal-title":"Adv. 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