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Hence, this paper demonstrates the effect of single, binary, and ternary ligands on TENG performance of cobalt\/cerium\u2010based (Co\u2500Ce) bimetallic MOFs utilizing 2\u2010methylimidazole (2Melm), terephthalic acid (BDC), and benzene tricarboxylic acid (BTC) as ligands. The detailed structural characterization revealed that varying ligand chemistries led to distinct MOF features affecting TENG performance. Single ligand bimetallic MOFs (designated as CoCe\u20102MeIm, CoCe\u2010BDC, CoCe\u2010BTC) has lower performance than binary ligand (designated as CoCe\u20102MeIm\u2010BDC, CoCe\u20102MeIm\u2010BTC, CoCe\u2010BDC\u2010BTC) and ternary ligand MOFs (designated as CoCe\u20102MeIm\u2010BDC\u2010BTC). Among all, the binary ligand MOF, CoCe\u20102MeIm\u2010BTC, shows the best results (598\u00a0V, 26.7\u00a0\u00b5A) due to the combined effect of imidazole ring and (\u2500COO\u2500) groups. This is attributed to lone pairs on nitrogen atoms and a delocalized \u03c0\u2010electron system in imidazole system in this material. CoCe\u2010BTC has the lowest results (31\u00a0V, 3.2\u00a0\u00b5A) due to the bulkier nature of the electron\u2010withdrawing (\u2500COO\u2500) groups and their impact on the \u03c0\u2010electron system of the benzene ring. This study showcases the potential of ligand chemistry manipulation to control triboelectric charge and thereby enhance MOF\u2010based TENG performance.<\/jats:p>","DOI":"10.1002\/advs.202404993","type":"journal-article","created":{"date-parts":[[2024,7,12]],"date-time":"2024-07-12T08:19:34Z","timestamp":1720772374000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Controlling Triboelectric Charge of MOFs by Leveraging Ligands Chemistry"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2830-8520","authenticated-orcid":false,"given":"Muhammad","family":"Noman","sequence":"first","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8829-0230","authenticated-orcid":false,"given":"Qazi Muhammad","family":"Saqib","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shahid","family":"Ameen","sequence":"additional","affiliation":[{"name":"Department of Chemistry Ulsan National Institute of Science and Technology (UNIST)  Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2007-9428","authenticated-orcid":false,"given":"Swapnil R.","family":"Patil","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3700-0883","authenticated-orcid":false,"given":"Chandrashekhar S.","family":"Patil","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5993-0988","authenticated-orcid":false,"given":"Jungmin","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youngbin","family":"Ko","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"BongSoo","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Ulsan National Institute of Science and Technology (UNIST)  Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5298-0122","authenticated-orcid":false,"given":"Jinho","family":"Bae","sequence":"additional","affiliation":[{"name":"Department of Ocean System Engineering Jeju National University  Jeju 63243 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,7,12]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-34385-4"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.comcom.2007.05.035"},{"key":"e_1_2_9_3_1","first-page":"1","volume":"5","author":"Kim S.","year":"2015","journal-title":"Int. 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