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The current challenge is to reduce high consumption of chemical reagents. Herein, a closed\u2010loop spent LABs paste (SLBP) recovery strategy is demonstrated through Na<jats:sub>2<\/jats:sub>MoO<jats:sub>4<\/jats:sub> consumption\u2010regeneration\u2010reuse. Experimental and DFT calculations verify that MoO<jats:sub>4<\/jats:sub><jats:sup>2\u2212<\/jats:sup> competes Pb\/Ca ions and weakens the metal\u2010oxygen bond of PbSO<jats:sub>4<\/jats:sub>\/CaSO<jats:sub>4<\/jats:sub>.2H<jats:sub>2<\/jats:sub>O in SLBP, facilitating PbMoO<jats:sub>4<\/jats:sub>\/CaMoO<jats:sub>4<\/jats:sub> formation and 99.13 wt% of SO<jats:sub>4<\/jats:sub><jats:sup>2\u2212<\/jats:sup> elimination. Pb of 99.97 wt% is obtained as zero\u2010carbon precursors (PbO<jats:sub>2<\/jats:sub> and PbMoO<jats:sub>4<\/jats:sub>) by green leaching coupled with re\u2010crystallization. The regeneration of Na<jats:sub>2<\/jats:sub>MoO<jats:sub>4<\/jats:sub> is realized at 600 \u2103 using LABs polypropylene shells and NaOH as reagents. Compared with the traditional smelting technologies, the temperature is reduced from \uff1e1000 to 600 \u00b0C. The extraction of Na<jats:sub>2<\/jats:sub>MoO<jats:sub>4<\/jats:sub> require only water, and satisfactory re\u2010used desulfurization efficiency (98.67 wt%) is achieved. For the residual Na<jats:sub>2<\/jats:sub>MoO<jats:sub>4<\/jats:sub> after first SLBP desulfurization, the desulfurization efficiency remains above 97.36 wt% after adding fresh reagents for two running cycles. The new principle enables the reuse of 99.83 wt% of Na<jats:sub>2<\/jats:sub>MoO<jats:sub>4<\/jats:sub> and the recycling of 95.27 wt% of Pb without generating wastewater and slags. The techno\u2010economic analysis indicates this strategy is efficient, economical, and environmentally\u2010friendly.<\/jats:p>","DOI":"10.1002\/advs.202405168","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T14:20:06Z","timestamp":1732112406000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Efficient Desulfurizer Recycling during Spent Lead\u2013Acid Batteries Paste Disposal by Zero\u2010Carbon Precursor Hypothermic Smelting"],"prefix":"10.1002","volume":"11","author":[{"given":"Fei","family":"Li","sequence":"first","affiliation":[{"name":"School of Environment and Energy South China University of Technology  Guangzhou 510006 China"},{"name":"School of Environmental Science and Engineering Sun Yat\u2010Sen University  Guangzhou 510275 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