{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T18:43:09Z","timestamp":1785177789149,"version":"3.55.0"},"reference-count":41,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2025,3,24]],"date-time":"2025-03-24T00:00:00Z","timestamp":1742774400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22201093"],"award-info":[{"award-number":["22201093"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of hollow fullerene\u2010like cages has always been an attractive goal for researchers. Nevertheless, such molecular design blueprints are often hampered by the unmet customization of assembly strategy and suitable five\u2010membered ring molecular tiles for building spheres. Herein, a novel spherical molecular cage V<jats:sub>60<\/jats:sub>\u2010MOP is successfully built by connecting 12 homo\u2010metallic pentagonal {V<jats:sub>5<\/jats:sub>S} tiles with benzene\u20101,3,5\u2010tricarboxylate (BTC) ligands through coordination\u2010driven self\u2010assembly and exhibits a similar geometry to the C<jats:sub>60<\/jats:sub> molecule. As far as is known, this {V<jats:sub>5<\/jats:sub>S} cluster with the shape of a hollow pentagram is entirely new and is first discovered in metal\u2013organic polyhetra (MOPs). The other two pentagonal motifs are also customized by inserting [VO<jats:sub>5<\/jats:sub>] or [MoO<jats:sub>5<\/jats:sub>] in the center of {V<jats:sub>5<\/jats:sub>S} through in situ modification, which also led to another isomorphic V<jats:sub>72<\/jats:sub>\u2010MOP and V<jats:sub>60<\/jats:sub>Mo<jats:sub>12<\/jats:sub>\u2010MOP fullerene\u2010like cages. The three spherical cages reported above all exhibit regular icosahedral symmetry. Notably, a fascinating structure V<jats:sub>66<\/jats:sub>\u2010MOP is constructed from two different pentagonal motifs {V<jats:sub>5<\/jats:sub>S} and {VV<jats:sub>5<\/jats:sub>S}, with reduced symmetry, although the molecule remains a sphere in appearance, which is rare in fullerene\u2010shaped structures. In addition, the series of fullerene\u2010like V\u2010MOPs are active in the oxidation of sulfides to produce sulfoxides or sulfones with high conversion.<\/jats:p>","DOI":"10.1002\/advs.202408863","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T18:53:10Z","timestamp":1742928790000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Self\u2010Assembly Engineering of Fullerene\u2010Like Polyhedra: V<sub>60<\/sub>, V<sub>66<\/sub>, V<sub>72<\/sub> From {MV<sub>5<\/sub>} Pentagonal Second Building Block"],"prefix":"10.1002","volume":"12","author":[{"given":"Hongmei","family":"Gan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Jilin University  Changchun Jilin 130024 China"},{"name":"Key Laboratory of Chemistry and Chemical Engineering on Heavy\u2010Carbon Resources Yili Normal University  Yining Xinjiang 835000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linyan","family":"Bao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Jilin University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Lab of Polyoxometalate Science of Ministry of Education Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baoshan","family":"Hou","sequence":"additional","affiliation":[{"name":"Key Lab of Polyoxometalate Science of Ministry of Education Northeast Normal University  Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinlong","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Lab of Polyoxometalate Science of Ministry of Education Northeast Normal University  Changchun Jilin 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