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However, the preparation of rare\u2010earth\u2010doped all\u2010inorganic perovskite is complex, and difficult to control, and the issue of thermal quenching poses significant challenges to its practical application. Here, in order to address these issues, a convenient photo\u2010induced synthesis method for CsPbCl\n                    <jats:sub>3<\/jats:sub>\n                    :Mn\/Yb nanocrystals (NCs) is proposed by decomposing carbon tetrachloride with 365\u00a0nm light to provide chloride ions and regulate the formation of perovskite at room temperature. The negative thermal quenching in the NIR emission is achieved through the energy transfer between Mn and Yb. The emission intensity of Yb enhances 3.2 times when the temperature rises to \u2248427 K. Furthermore, with the help of the orange emission from the Mn\n                    <jats:sup>2+<\/jats:sup>\n                    ions and the NIR emission from the Yb\n                    <jats:sup>3+<\/jats:sup>\n                    ions, visible to NIR light emitting diode\u00a0(LED) devices are constructed and applied in orange light illumination and night vision imaging. This study enriches the preparation methods and chemical research on perovskite doping, which may open up new opportunities for the widespread application of perovskite\u2010based materials or device engineering.\n                  <\/jats:p>","DOI":"10.1002\/advs.202408927","type":"journal-article","created":{"date-parts":[[2024,12,4]],"date-time":"2024-12-04T10:10:42Z","timestamp":1733307042000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Photo\u2010Induced Synthesis of Ytterbium and Manganese\u2010Doped CsPbCl\n                    <sub>3<\/sub>\n                    Nanocrystals for Visible to Near\u2010Infrared Photoluminescence with Negative Thermal Quenching"],"prefix":"10.1002","volume":"12","author":[{"given":"Xiaochen","family":"Fang","sequence":"first","affiliation":[{"name":"College of Materials Engineering Fujian Agriculture and Forestry University  Fuzhou 350002 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