{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T06:55:48Z","timestamp":1792220148961,"version":"4.4.0"},"reference-count":53,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2025,2,19]],"date-time":"2025-02-19T00:00:00Z","timestamp":1739923200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004377","name":"Hong Kong Polytechnic University","doi-asserted-by":"publisher","award":["Q\u2010CDBU"],"award-info":[{"award-number":["Q\u2010CDBU"]}],"id":[{"id":"10.13039\/501100004377","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF\u20102022H1D3A2A01096400"],"award-info":[{"award-number":["NRF\u20102022H1D3A2A01096400"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Seawater electrolysis holds great promise for sustainable, green hydrogen production but faces challenges of high overpotentials and competing chlorine evolution reaction (CER). Replacing the oxygen evolution reaction with the methanol oxidation reaction (MOR) presents a compelling alternative due to its lower anodic potential which mitigates the risk of CER. While NiOOH is known for its MOR activity, its performance is limited by sluggish non\u2010electrochemical kinetics and Cl\u2010induced degradation. Herein, a MoO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    \u2010modified NiOOH electrocatalyst is reported that significantly enhances MOR\u2010assisted seawater splitting efficiency. In situ leached MoO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    from the heterojunction optimizes methanol adsorption and facilitates proton migration, thereby accelerating the non\u2010electrochemical steps in MOR. Additionally, the adsorbed MoO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    effectively repels Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    , protecting the electrodes from Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010induced corrosion. The MOR\u2010assisted electrolyzer using NiMo||Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    \/NiMoO\u2084 requires only 1.312\u00a0V to achieve 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , substantially lower than conventional alkaline seawater electrolysis (1.576\u00a0V). Furthermore, it demonstrates remarkable stability, sustaining high current densities (up to 1.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) for over 130\u00a0h. This work presents a promising strategy for designing high\u2010performance electrocatalysts for efficient and sustainable green hydrogen production from seawater.\n                  <\/jats:p>","DOI":"10.1002\/advs.202410911","type":"journal-article","created":{"date-parts":[[2025,2,20]],"date-time":"2025-02-20T01:51:33Z","timestamp":1740016293000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Molybdate\u2010Modified NiOOH for Efficient Methanol\u2010Assisted Seawater Electrolysis"],"prefix":"10.1002","volume":"12","author":[{"given":"Zhen","family":"Li","sequence":"first","affiliation":[{"name":"Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic University  Hung Hom Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youbin","family":"Zheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Dielectric and Electrolyte Functional Material School of Resources and Materials Northeastern University at Qinhuangdao  Qinhuangdao Hebei 066004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhan","family":"Zu","sequence":"additional","affiliation":[{"name":"Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy The Hong Kong Polytechnic University  Hung Hom Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang","family":"Dong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Dielectric and Electrolyte Functional Material School of Resources and Materials Northeastern University at Qinhuangdao  Qinhuangdao Hebei 066004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6119-4780","authenticated-orcid":false,"given":"Lawrence Yoon 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