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Among them, tetrafluoromethane (CF\n                    <jats:sub>4<\/jats:sub>\n                    ) is the simplest and most abundant PFC in the atmosphere. However, the highest C\u2500F bond energy and its highly symmetrical structure make it particularly challenging to decompose. In this work, a yolk\u2013shell Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    micro\u2010reactor is developed to enhance the catalytic hydrolysis performance of CF\n                    <jats:sub>4<\/jats:sub>\n                    by creating a local autothermic environment. Finite element simulations predict that the yolk\u2013shell Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    micro\u2010reactor captures the heat released during the catalytic hydrolysis of CF\n                    <jats:sub>4<\/jats:sub>\n                    , resulting in a local autothermic environment within the yolk\u2013shell structure that is 50 \u00b0C higher than the set temperature. The effectiveness of this local autothermic environment is experimentally confirmed by in situ Raman spectroscopy. As a result, the obtained yolk\u2013shell Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    micro\u2010reactor achieves 100% CF\n                    <jats:sub>4<\/jats:sub>\n                    conversion at a considerably low temperature of 580 \u00b0C for over 150\u00a0h, while hollow and solid Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    structures required higher temperatures of 610 and 630 \u00b0C, respectively, to achieve the same conversion rate, demonstrating the potential of yolk\u2013shell Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    micro\u2010reactor to significantly reduce the energy requirements for PFCs degradation and contribute to more sustainable and effective environmental remediation strategies.\n                  <\/jats:p>","DOI":"10.1002\/advs.202413203","type":"journal-article","created":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T13:10:15Z","timestamp":1736514615000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Catalytic Hydrolysis of Perfluorinated Compounds in a Yolk\u2013Shell Micro\u2010Reactor"],"prefix":"10.1002","volume":"12","author":[{"given":"Jialin","family":"Zheng","sequence":"first","affiliation":[{"name":"Hunan Joint International Research Center for Carbon Dioxide Resource Utilization School of Physics Central South University  Changsha Hunan 410083 P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hunan Joint International Research Center for Carbon Dioxide Resource Utilization School of Physics Central South University  Changsha Hunan 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heping","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Resource Environment and Safety Engineering University of South China  Hengyang Hunan 421001 P. R. 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