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While numerous approaches are developed for the generation of FA but the requirement of harsh reaction conditions to achieve them is unavoidable. On the other hand, the world production of biomass is estimated at\u00a0146 billion metric tons\u00a0per year and that can be considered as a prospective source of FA and their salts. Additionally, cellulose accounts for approximately\u00a035\u201345%\u00a0of the biomass composition. Considering this, a visible\u2010light\u2010mediated approach is presented to produce formate directly from biomass at room temperature as well as at atmospheric pressure. In this approach, selective generation of hydroxyl radical has been achieved which later converted sugars, cellulose, and hemicellulose into formate. Furthermore, the conversion of cellulose\u2010rich daily\u2010life materials such as discarded paper into the product through a series of flow experiments is demonstrated. Finally, mechanistic investigations including electron paramagnetic resonance (EPR)\u00a0spectroscopy, and density functional theory (DFT) calculations are conducted to gain insights into the underlying reaction mechanism.<\/jats:p>","DOI":"10.1002\/advs.202415339","type":"journal-article","created":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T08:57:40Z","timestamp":1743497860000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["A Transition Metal\u2010Free Approach for the Conversion of Real\u2010Life Cellulose\u2010Based Biomass into Formate"],"prefix":"10.1002","volume":"12","author":[{"given":"Tong","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Antwerp  Antwerp 2020 Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng","family":"Ren","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Antwerp  Antwerp 2020 Belgium"},{"name":"Department of Chemistry University of Bayreuth  95447 Bayreuth Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuman","family":"Qin","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Antwerp  Antwerp 2020 Belgium"},{"name":"Department of Chemistry University of Bayreuth  95447 Bayreuth Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thanh Huyen","family":"Vuong","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institut f\u00fcr Katalyse e.V. 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