{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T12:50:29Z","timestamp":1793364629820,"version":"4.5.0"},"reference-count":36,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,1,21]],"date-time":"2025-01-21T00:00:00Z","timestamp":1737417600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22325204"],"award-info":[{"award-number":["22325204"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The unavoidable self\u2010reduction of Bismuth (Bi)\u2010based catalysts to zero\u2010valence Bi often results in detrimental adsorption of OCHO\n                    <jats:sup>*<\/jats:sup>\n                    , leading to unsatisfactory selectivity of HCOOH in the electroreduction of carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ). A novel Bi\u2010tannin (Bi\u2010TA) complex is developed, which undergoes in situ reconstruction into a Bi\/Bi\u2082O\u2082CO\u2083 phase during CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. This reconstructed catalyst exhibits high activity and selectivity, achieving a Faradaic Efficiency (FE) for formate production exceeding 90%, peaking at 96%. Operando spectroscopic and theoretical analyses reveal that the Bi\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    active site in Bi\/Bi\u2082O\u2082CO\u2083 significantly enhances the formation of the OCHO\n                    <jats:sup>*<\/jats:sup>\n                    intermediate, crucial for formate production. The study offers a promising approach to overcoming the limitations of Bi\u2010based catalysts in CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to formate.\n                  <\/jats:p>","DOI":"10.1002\/advs.202415616","type":"journal-article","created":{"date-parts":[[2025,1,21]],"date-time":"2025-01-21T13:25:18Z","timestamp":1737465918000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["High\u2010Performance Bi\u2010Based Catalysts for CO\u2082 Reduction: In Situ Formation of Bi\/Bi\u2082O\u2082CO\u2083 and Enhanced Formate Production"],"prefix":"10.1002","volume":"12","author":[{"given":"Ben","family":"Li","sequence":"first","affiliation":[{"name":"Advanced Materials and Catalysis Group ZJU\u2010Zhejiang Xinhua Low\u2010Carbon Research Center State Key Laboratory of Clean Energy Utilization Institute of Catalysis Department of Chemistry Zhejiang University  Hangzhou 310058 P. 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