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Herein, a sub\u2010nanometric Pt ensemble catalyst with a diverse array of active sites is constructed via a dual\u2010confinement strategy, which exhibits superior activity and durability with minimal Pt loading (0.13 wt.%). Simultaneously, the roles of different Pt sites at the atomic scale are determined through in situ characterization methods and density functional theory (DFT) calculations. Specifically, Pt top sites predominantly serve as pivotal centers for O\u2550O bond activation, whereas Pt\u2212O\u2212Si interfacial sites primarily govern the activation of H\u2500OH and C\u2500H bonds. The reactive oxygen species (O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    , and \u2212OH) generated from O\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O activation synergistically enhance formaldehyde (HCHO) oxidation and shorten the reaction pathway. This study sheds light on a better understanding and rational design of catalyst active sites via precise synthesis of multi\u2010site ensembles or discerning the distinct contributions of various catalytic sites.\n                  <\/jats:p>","DOI":"10.1002\/advs.202415937","type":"journal-article","created":{"date-parts":[[2025,2,18]],"date-time":"2025-02-18T14:00:10Z","timestamp":1739887210000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Engineering Multi\u2010Site Platinum Ensembles Synergistically Boosts Catalysis"],"prefix":"10.1002","volume":"12","author":[{"given":"Tao","family":"Dong","sequence":"first","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510006 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fei","family":"Xiao","sequence":"additional","affiliation":[{"name":"School of Environmental Science and 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