{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T18:51:34Z","timestamp":1789584694834,"version":"build-2803163510"},"reference-count":66,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T00:00:00Z","timestamp":1745625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100020581","name":"Fondazione AIRC per la ricerca sul cancro ETS","doi-asserted-by":"publisher","award":["25681"],"award-info":[{"award-number":["25681"]}],"id":[{"id":"10.13039\/100020581","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100024015","name":"Dipartimento di Scienze Chimiche, Universit\u00e0 degli Studi di Padova","doi-asserted-by":"publisher","award":["DYNAMO"],"award-info":[{"award-number":["DYNAMO"]}],"id":[{"id":"10.13039\/501100024015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Laser ablation in liquid (LAL) is a reference technique for the synthesis of multicomponent non\u2010equilibrium nanomaterials which have potentially disruptive properties in photonics, nanomedicine, and catalysis. Yet, ablation dynamics is poorly understood regarding the multielement matter and, therefore, the remarkable potential of LAL for controlling the local atomic structure of metastable nanophases remains largely unexploited. Here, the dynamics of LAL are investigated with non\u2010equilibrium gold\u2010iron nanoalloys generated in the presence of gas\u2010evolving additives, which drive the formation of different nanostructures. With analytical electron microscopy, the structure in the different conditions is properly identified through complete segregation into oxide\u2010metal heterostructures, precipitation of nanoclusters within the nanoalloys, or ordered solid solutions. To elucidate the unforeseen effects of the solutes on the atomic structure of nanoalloys, the early and full dynamics of LAL is investigated with time\u2010resolved experiments, leading to the pivotal evidence that alloying of metastable compounds with different chemical reactivity is favored by decreasing the pressure of the shockwave front. The resulting picture indicates LAL with gas\u2010evolving additives as a strategy for molding the atomic structure of non\u2010equilibrium nanoalloys, opening the way to the development of a library of advanced nanomaterials otherwise inaccessible.<\/jats:p>","DOI":"10.1002\/advs.202416035","type":"journal-article","created":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T06:41:03Z","timestamp":1745649663000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Time\u2010Resolved Dynamics of Laser Ablation in Liquid with Gas\u2010Evolving Additives: Toward Molding the Atomic Structure of Nonequilibrium Nanoalloys"],"prefix":"10.1002","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8942-4026","authenticated-orcid":false,"given":"Vito","family":"Coviello","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Universit\u00e0 di Padova  via Marzolo 1 Padova I\u201035131 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Catherine","family":"Reffatto","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Universit\u00e0 di Padova  via Marzolo 1 Padova I\u201035131 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mehdi W.","family":"Fawaz","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1 UMR 5306 CNRS Institut Lumi\u00e8re Mati\u00e8re  Villeurbanne F\u201069100 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benoit","family":"Mahler","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1 UMR 5306 CNRS Institut Lumi\u00e8re Mati\u00e8re  Villeurbanne F\u201069100 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arnaud","family":"Sollier","sequence":"additional","affiliation":[{"name":"CEA DAM DIF  Arpajon F\u201091297 France"},{"name":"Universit\u00e9 Paris\u2010Saclay CEA Laboratoire Mati\u00e8re en Conditions Extr\u00eames  Bruy\u00e8res\u2010 Le\u2010Chatel F\u201091680 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bratislav","family":"Lukic","sequence":"additional","affiliation":[{"name":"ESRF\u2010The European Synchrotron  CS40220 Grenoble F\u201038043 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Rack","sequence":"additional","affiliation":[{"name":"ESRF\u2010The European Synchrotron  CS40220 Grenoble F\u201038043 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7553-2907","authenticated-orcid":false,"given":"David","family":"Amans","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Claude Bernard Lyon 1 UMR 5306 CNRS Institut Lumi\u00e8re Mati\u00e8re  Villeurbanne F\u201069100 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9937-7005","authenticated-orcid":false,"given":"Vincenzo","family":"Amendola","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Universit\u00e0 di Padova  via Marzolo 1 Padova I\u201035131 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,26]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377-022-00904-7"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c01069"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202405457"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CP42895D"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6595\/ab3dbe"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP00608D"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00339-023-06525-0"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377-022-00751-6"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2016.08.017"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201601231"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CP53748J"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c03614"},{"key":"e_1_2_8_13_1","first-page":"585, 267","author":"Guadagnini A.","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45137-x"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377-024-01614-y"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105869"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c18999"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307060"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06456-y"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-01967-0"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NR03962C"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c02138"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NH00332K"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NR05117J"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoso.2024.101246"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP00279F"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2016.10.023"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2021.151592"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4942389"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1143\/APEX.3.035201"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.29026\/oea.2022.210053"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.8b01585"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR01500H"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11433-021-1857-1"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep16313"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3642968"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CP02663K"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.3762\/bjnano.15.54"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202300089"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.8b11087"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0077976"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130970"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.9b02396"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano12040649"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano9020198"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201900447"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202005087"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202304359"},{"key":"e_1_2_8_49_1","volume-title":"Room\u2010Temperature Laser Synthesis in Liquid of Oxide, Metal\u2010Oxide Core\u2010Shells, and Doped Oxide Nanoparticles","author":"Amendola V.","year":"2020"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1139\/v73-028"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1121\/1.415878"},{"key":"e_1_2_8_52_1","first-page":"209","volume-title":"High Pressure Physics and Chemistry","author":"Duvall G. E.","year":"1963"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-6031(73)80019-X"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevFluids.4.044003"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.109.044501"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp502327c"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0035678"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-319-70831-7_3"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/0041-624X(93)90020-Z"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1017\/jfm.2013.456"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP01214J"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c09970"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-021-06731-2"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp1090944"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00468"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.366113"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202416035","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T09:45:27Z","timestamp":1759743927000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202416035"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,26]]},"references-count":66,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2025,6]]}},"alternative-id":["10.1002\/advs.202416035"],"URL":"https:\/\/doi.org\/10.1002\/advs.202416035","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,26]]},"assertion":[{"value":"2024-12-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2416035"}}