{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T03:39:29Z","timestamp":1790480369441,"version":"4.1.0"},"reference-count":42,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2025,3,26]],"date-time":"2025-03-26T00:00:00Z","timestamp":1742947200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003701","name":"Korea Institute of Machinery and Materials","doi-asserted-by":"publisher","award":["NK255F"],"award-info":[{"award-number":["NK255F"]}],"id":[{"id":"10.13039\/501100003701","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008783","name":"National Research Council of Science and Technology","doi-asserted-by":"publisher","award":["2710024139"],"award-info":[{"award-number":["2710024139"]}],"id":[{"id":"10.13039\/501100008783","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010metal anodes are essential for the advancement of next\u2010generation batteries. However, their practical use is largely hindered by the uncontrollable growth of dendrites and intricate problems associated with fabricating anodes that meet capacity requirements. Here, it is demonstrated that an ultrathin ZnF\n                    <jats:sub>2<\/jats:sub>\n                    layer deposited on the copper foil can produce a novel and efficient current collector to address these challenges. It is observed that ZnF\n                    <jats:sub>2<\/jats:sub>\n                    can be transformed into LiZn alloy and LiF salt in one step by simple electrochemical activation. The resulting LiZn alloy exhibits high lithiophilicity, which reduces overpotential and promotes uniform lithium nucleation, while the LiF salt enhances the solid electrolyte interphase, ensuring uniform lithium growth. This synergistic effect led to a dendrite\u2010free, densely packed lithium anode with an extended lifespan, achieving over 900\u00a0h in symmetric cells at a high current density of 3\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and a high cut\u2010off capacity of 3 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Furthermore, full cells utilizing the lithium anode (Li capacity of 6 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) paired with LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    cathodes (mass loading of 11.5\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) demonstrates drastically improved rate capability and excellent cycling stability. This approach holds great promise for developing safer and more efficient lithium\u2010metal\u2010based batteries for future energy storage solutions.\n                  <\/jats:p>","DOI":"10.1002\/advs.202416426","type":"journal-article","created":{"date-parts":[[2025,3,29]],"date-time":"2025-03-29T09:49:58Z","timestamp":1743241798000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Taming Lithium Nucleation and Growth on Cu Current Collector by Electrochemical Activation of ZnF\n                    <sub>2<\/sub>\n                    Layer"],"prefix":"10.1002","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7727-2499","authenticated-orcid":false,"given":"Viet Phuong","family":"Nguyen","sequence":"first","affiliation":[{"name":"Nanomechatronics University of Science and Technology (UST)  217 Gajeong\u2010ro Daejeon 34113 Republic of Korea"},{"name":"Department of Nanomechanics Korea Institute of Machinery &amp; Materials (KIMM)  156 Gajeongbuk\u2010ro Daejeon 34103 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5275-8671","authenticated-orcid":false,"given":"Hyung Cheoul","family":"Shim","sequence":"additional","affiliation":[{"name":"Department of Nanomechanics Korea Institute of Machinery &amp; Materials (KIMM)  156 Gajeongbuk\u2010ro Daejeon 34103 Republic of Korea"},{"name":"School of Materials Science and Semiconductor Engineering University of Ulsan, 93 Daehak\u2010ro, Nam\u2010gu  Ulsan 44610 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Young\u2010Woon","family":"Byeon","sequence":"additional","affiliation":[{"name":"Advanced Analysis and Data Center Korea Institute of Science and Technology (KIST)  Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jae\u2010Hyun","family":"Kim","sequence":"additional","affiliation":[{"name":"Nanomechatronics University of Science and Technology (UST)  217 Gajeong\u2010ro Daejeon 34113 Republic of Korea"},{"name":"Department of Nanomechanics Korea Institute of Machinery &amp; Materials (KIMM)  156 Gajeongbuk\u2010ro Daejeon 34103 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0732-4473","authenticated-orcid":false,"given":"Seung\u2010Mo","family":"Lee","sequence":"additional","affiliation":[{"name":"Nanomechatronics University of Science and Technology (UST)  217 Gajeong\u2010ro Daejeon 34113 Republic of Korea"},{"name":"Department of Nanomechanics Korea Institute of Machinery &amp; Materials (KIMM)  156 Gajeongbuk\u2010ro Daejeon 34103 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,26]]},"reference":[{"key":"e_1_2_10_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2017.16"},{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0305-8"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00833-6"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201803722"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA02431A"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnl2.147"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/admt.201900806"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407648"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202311301"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/ece2.40"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202400007"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2022.100996"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202301288"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.8b04919"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201905620"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0640-7"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.06.008"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2020.104746"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c08864"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn1818"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.10"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/eom2.12478"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202002736"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01140E"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207902"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b02527"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202103972"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.34133\/research.0267"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.136243"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00156B"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201802534"},{"key":"e_1_2_10_32_1","volume":"62","author":"Zeng Y.","year":"2023","journal-title":"Angew. 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