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The tenuous trade\u2010off between the strong metal\u2013support interaction (SMSI)\u2010induced Cu\u2013ZnO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    interface and the accessible Cu surface strongly affects the activity of the final catalyst. Successes in the control of oxide migration on adsorbate\u2010induced SMSI catalysts have motivated this to develop a supercritical CO\n                    <jats:sub>2<\/jats:sub>\n                    activation strategy to synchronously perfect the Cu\n                    <jats:sup>0<\/jats:sup>\n                    \u2013O\u2013Zn\n                    <jats:italic>\n                      <jats:sup>\u03b4<\/jats:sup>\n                    <\/jats:italic>\n                    <jats:sup>+<\/jats:sup>\n                    interface and Cu\n                    <jats:sup>0<\/jats:sup>\n                    \u2013Cu\n                    <jats:sup>+<\/jats:sup>\n                    surface sites through the manipulation of the adsorbate diffusion kinetics, which involves\n                    <jats:sup>*<\/jats:sup>\n                    OC\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    and \u201cside\u2010on\u201d fixed CO\n                    <jats:sub>2<\/jats:sub>\n                    species. This findings illustrate that the adsorbate on ZnO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    can facilitate its secondary uniform nucleation and induce a Zn\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    spinel phase and that CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption on metallic Cu\n                    <jats:sup>0<\/jats:sup>\n                    produces an activated Cu\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    O amorphous shell. Such a structural evolution unlocks a dual\u2010response pathway in methanol synthesis, thus enabling Cu\/ZnO\/Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    with a twofold increase in catalytic activity. This atomic\u2010level design of active sites and understanding of supercritical CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010induced structural evolution will guide the future development of high\u2010performance supported metal catalysts.\n                  <\/jats:p>","DOI":"10.1002\/advs.202500118","type":"journal-article","created":{"date-parts":[[2025,3,9]],"date-time":"2025-03-09T09:06:49Z","timestamp":1741511209000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Supercritical CO\n                    <sub>2<\/sub>\n                    Activation Enables an Exceptional Methanol Synthesis Activity Over the Industrial Cu\/ZnO\/Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Catalyst"],"prefix":"10.1002","volume":"12","author":[{"given":"Yannan","family":"Zhou","sequence":"first","affiliation":[{"name":"Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College  Zhengzhou Henan 450006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyun","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Zhengzhou University  Zhengzhou Henan 450052 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yushun","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Henan University of Science and Technology  Luoyang Henan 471023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruijie","family":"Liu","sequence":"additional","affiliation":[{"name":"Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College  Zhengzhou Henan 450006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shouren","family":"Zhang","sequence":"additional","affiliation":[{"name":"Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional Materials Huanghe Science and Technology College  Zhengzhou Henan 450006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2467-8751","authenticated-orcid":false,"given":"Jianfang","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Physics The Chinese University of Hong Kong  Shatin Hong Kong SAR 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,7]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12183"},{"key":"e_1_2_8_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00289-y"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00148"},{"key":"e_1_2_8_3_1","unstructured":"C. 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