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In this study, FeNiCrMnCo multicomponent alloy (MCA) is integrated with GaN nanowires (NW's) for photo\u2010thermal\u2010coupled catalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation. The MCA\/GaN NW's nanohybrid demonstrates a considerable methane production rate of 199 mmol\u2219g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2219h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with an impressive selectivity of 93% under white light irradiation of 3 W\u2219cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 290\u00a0\u00b0C by external heating. The turnover number approaches 20,160 mole CH\n                    <jats:sub>4<\/jats:sub>\n                    per mole of MCA over a continuous operation period of 120 h, showcasing remarkable stability. Mechanistic investigations reveal that the unique MCA provides a flexible platform for tailoring the electronic and catalytic properties to optimize the adsorption and activation of CO\u2082 and H\u2082, thus leading to efficient and selective CO\u2082 methanation. This study presents an industry\u2010friendly architecture for photo\u2010thermal\u2010coupled CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation into high\u2010value fuels and chemicals by coupling a noble\u2010metal\u2010free multicomponent alloy with GaN NWs, paving the way for advancements in sustainable energy conversion through CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization.\n                  <\/jats:p>","DOI":"10.1002\/advs.202501298","type":"journal-article","created":{"date-parts":[[2025,4,17]],"date-time":"2025-04-17T14:30:01Z","timestamp":1744900201000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Unlocking Methane Generation via Photo\u2010Thermal\u2010Coupled CO\n                    <sub>2<\/sub>\n                    Hydrogenation by Integrating FeNiCrMnCo Multicomponent Alloy with GaN Nanowires"],"prefix":"10.1002","volume":"12","author":[{"given":"Muhammad Salman","family":"Nasir","sequence":"first","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Mining and Materials Engineering McGill University  3610 University Street Montreal QC H3A0C9 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haotian","family":"Ye","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Artificial Microstructure and Mesoscopic Physics School of Physics Nano\u2010Optoelectronics Frontier Center of Ministry of Education (NFC\u2010MOE) Peking University  Beijing 10087 China"},{"name":"Peking University Yangtze Delta Institute of Optoelectronics  Nantong Jiangsu 226010 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinglin","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ping","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Artificial Microstructure and Mesoscopic Physics School of Physics Nano\u2010Optoelectronics Frontier Center of Ministry of Education (NFC\u2010MOE) Peking University  Beijing 10087 China"},{"name":"Peking University Yangtze Delta Institute of Optoelectronics  Nantong Jiangsu 226010 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