{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T00:49:00Z","timestamp":1789692540972,"version":"4.0.1"},"reference-count":58,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T00:00:00Z","timestamp":1745625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22206187"],"award-info":[{"award-number":["22206187"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["42407608"],"award-info":[{"award-number":["42407608"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22204166"],"award-info":[{"award-number":["22204166"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFD1700300"],"award-info":[{"award-number":["2024YFD1700300"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFB3201400"],"award-info":[{"award-number":["2021YFB3201400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004739","name":"Youth Innovation Promotion Association of the Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["2023469"],"award-info":[{"award-number":["2023469"]}],"id":[{"id":"10.13039\/501100004739","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012152","name":"National Postdoctoral Program for Innovative Talents","doi-asserted-by":"publisher","award":["BX20230214"],"award-info":[{"award-number":["BX20230214"]}],"id":[{"id":"10.13039\/501100012152","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012152","name":"National Postdoctoral Program for Innovative Talents","doi-asserted-by":"publisher","award":["BX20230370"],"award-info":[{"award-number":["BX20230370"]}],"id":[{"id":"10.13039\/501100012152","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Atomic\u2010level catalysts are extensively applied in heterogeneous catalysis fields. However, it is a general but ineluctable issue that active metal atoms may migrate, aggregate, deactivate, or leach during reaction processes, suppressing their catalytic performances. Designing superior intrinsic\u2010structural stability of atomic\u2010level catalysts with high activity and revealing their dynamic structure evolution is vital for their wide applications in complex reactions or harsh conditions. Herein, high\u2010stable Pd\u2500Cu dual\u2010atom catalysts with PdN\n                    <jats:sub>3<\/jats:sub>\n                    \u2500CuN\n                    <jats:sub>3<\/jats:sub>\n                    coordination structure are engineered via strong chelation of Cu\n                    <jats:sup>2+<\/jats:sup>\n                    \u2010ions with electron pairs from palladium\u2010source, achieving the highest turnover frequency under the lowest overpotential for Cr(VI) electrocatalytic reduction detection in strong\u2010acid electrolytes. In situ X\u2010ray absorption fine structure spectra reveal dynamic \u201cspring\u2010effect\u201d of Cu\u2500Pd and Cu\u2500N bonds that are reversibly stretched with potential changes and can be recovered at 0.6\u00a0V for regeneration. The modulated electron\u2010orbit coupling effect of Pd\u2500Cu pairs prevents Cu\u2010atoms from aggregating as metallic nanoparticles. Pd\u2500Cu dual\u2010atoms interact with two O atoms of H\n                    <jats:sub>2<\/jats:sub>\n                    CrO\n                    <jats:sub>4<\/jats:sub>\n                    , forming stable bridge configurations and transferring electrons to promote Cr\u2500O bond dissociation, which prominently decreases reaction energy barriers. This work provides a feasible route to boost the stability and robustness of metal single\u2010atoms that are easily affected by reaction conditions for sustainable catalytic applications.\n                  <\/jats:p>","DOI":"10.1002\/advs.202501393","type":"journal-article","created":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T06:16:42Z","timestamp":1745648202000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Potential\u2010Driven Dynamic Spring\u2010Effect of Pd\u2500Cu Dual\u2010Atoms Empowered Stability and Activity for Electrocatalytic Reduction"],"prefix":"10.1002","volume":"12","author":[{"given":"Pei\u2010Hua","family":"Li","sequence":"first","affiliation":[{"name":"Institute of Environment Hefei Comprehensive National Science Center  Hefei 230088 P. R. China"},{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan\u2010Fan","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zong\u2010Yin","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Liang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong\u2010Huan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Cai","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi\u2010Hao","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Yi","family":"Lin","sequence":"additional","affiliation":[{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute of Environment Hefei Comprehensive National Science Center  Hefei 230088 P. R. China"},{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangyu","family":"Xiao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organic Compound Pollution Control Engineering (MOE) School of Environmental and Chemical Engineering Shanghai University  Shanghai 200444 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing Synchrotron Radiation Facility Institute of High Energy Physics Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Qing","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Environment Hefei Comprehensive National Science Center  Hefei 230088 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0395-4892","authenticated-orcid":false,"given":"Xing\u2010Jiu","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute of Environment Hefei Comprehensive National Science Center  Hefei 230088 P. R. China"},{"name":"Key Laboratory of Environmental Optics and Technology And Environmental Materials and Pollution Control Laboratory Institute of Solid State Physics HFIPS, Chinese Academy of Sciences  Hefei 230031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,26]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202307853"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202219242"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c01287"},{"key":"e_1_2_8_2_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2020.07.032"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209654"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c01637"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305964"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c09919"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2022.08.021"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.01.019"},{"key":"e_1_2_8_8_1","first-page":"318","volume":"7","author":"Chen H.","year":"2024","journal-title":"Matter"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c06827"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304713"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304412"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409079"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202406807"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202206263"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202004319"},{"key":"e_1_2_8_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206569"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300020"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02262"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c03475"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410457"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c02710"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2021.12.015"},{"key":"e_1_2_8_18_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2022.07.031"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407974"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c12576"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408914"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.04.019"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c07223"},{"key":"e_1_2_8_21_2","volume":"18","author":"Liu L.","year":"2024","journal-title":"ACS Nano"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40177-1"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202411543"},{"key":"e_1_2_8_22_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42756-8"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC05910F"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300905"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/adhm.202403920"},{"key":"e_1_2_8_24_3","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC02469A"},{"key":"e_1_2_8_24_4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304646"},{"key":"e_1_2_8_24_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212329"},{"key":"e_1_2_8_24_6","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA04368H"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411396"},{"key":"e_1_2_8_25_2","volume":"146","author":"Lu Y.","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211373"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2023.131148"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.166268"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202209283"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010159"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07208"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709803"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42794-2"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38777-y"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202206887"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313099"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0008-y"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04231"},{"key":"e_1_2_8_39_1","first-page":"74","volume":"65","author":"Welch C. M.","year":"2005","journal-title":"Talanta"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202501393","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T15:04:29Z","timestamp":1759763069000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202501393"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,26]]},"references-count":58,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2025,7]]}},"alternative-id":["10.1002\/advs.202501393"],"URL":"https:\/\/doi.org\/10.1002\/advs.202501393","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,26]]},"assertion":[{"value":"2025-01-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2501393"}}