{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T02:16:53Z","timestamp":1790821013142,"version":"4.1.0"},"reference-count":71,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T00:00:00Z","timestamp":1747699200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T00:00:00Z","timestamp":1747699200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012253","name":"Guangxi University","doi-asserted-by":"publisher","award":["ZX1080030424009"],"award-info":[{"award-number":["ZX1080030424009"]}],"id":[{"id":"10.13039\/501100012253","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012253","name":"Guangxi University","doi-asserted-by":"publisher","award":["ZX1080030424008"],"award-info":[{"award-number":["ZX1080030424008"]}],"id":[{"id":"10.13039\/501100012253","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22061005"],"award-info":[{"award-number":["22061005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Using aggregation\u2010induced emission luminous (AIEgens) containing dynamic molecular rotor structures as linkers to construct flexible smart luminescent metal\u2013organic frameworks (MOFs) has become a transformative approach to constructing artificial intelligence color\u2010changing materials. Herein, 4\u2032,4\u2033,4\u2032\u2033,4\u2033\u2033\u2010(ethene\u20101,1,2,2\u2010tetrayl)tetrabiphenyl\u20104\u2010carboxylic acid (H\n                    <jats:sub>4<\/jats:sub>\n                    TPPE) is selected as a linker, and octahedral Zr\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (OH)\n                    <jats:sub>8<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>4<\/jats:sub>\n                    cluster are used as secondary building unit (SBU) to construct the first smart luminescent MOF (Zr\u2010TPE\u2010MOF) that can be driven by CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    or CH\n                    <jats:sub>3<\/jats:sub>\n                    COOH vapor for respiration. It is worth noting that Zr\u2010TPE\u2010MOF can absorb trace amounts of CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    or CH\n                    <jats:sub>3<\/jats:sub>\n                    COOH vapor into the pores through respiration and shows a blue shift of the emission wavelength up to 479\u00a0nm and an increase of emission intensity by nearly three times. In addition, the thermochromic behavior of Zr\u2010TPE\u2010MOF is not obvious in the temperature range of 80\u2013350\u00a0K, but it has obvious thermofluorochromics behavior in the temperature range of 350\u2013470\u00a0K. Zr\u2010TPE\u2010MOF showed highly sensitive and visualized smart photoresponse to the highly toxic Cr\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    , with a detection limit as low as 7.49\u00a0\u00b5\n                    <jats:sc>m<\/jats:sc>\n                    . Benefiting from the porous framework structure and organic\u2013inorganic hybrid characteristics of Zr\u2010TPE\u2010MOF, it has excellent ROS generation ability and has excellent application prospects in photodynamic sterilization and rapid degradation of colored dyes.\n                  <\/jats:p>","DOI":"10.1002\/advs.202501824","type":"journal-article","created":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T06:40:08Z","timestamp":1747723208000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Respiration Drives Dynamic Metal\u2013Organic Framework for Smart Photoresponse to Volatile Toxic Vapors and Their Photodynamic Sterilization"],"prefix":"10.1002","volume":"12","author":[{"given":"Yun\u2010Lan","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Guangxi Normal University  Guilin 541004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3664-4022","authenticated-orcid":false,"given":"Hai\u2010Ling","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Guangxi Key Laboratory of Electrochemical Energy Materials Guangxi University  Nanning 530004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ju\u2010Fen","family":"Ai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Guangxi Normal University  Guilin 541004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guan\u2010Huang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Guangxi Normal University  Guilin 541004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hua\u2010Hong","family":"Zou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Guangxi Normal University  Guilin 541004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fu\u2010Pei","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Guangxi Normal University  Guilin 541004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1968-4855","authenticated-orcid":false,"given":"Zhong\u2010Hong","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Guangxi Key Laboratory of Electrochemical Energy Materials Guangxi University  Nanning 530004 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,20]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06849-0"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01518-6"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00828"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00521J"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00605"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mser.2024.100874"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110300"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05356-y"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00778D"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae342"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60483G"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42114-022-00432-3"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213651"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213260"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00095A"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.143290"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2025.141482"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c05180"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c04357"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2023.100096"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2023.100018"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318722"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00885F"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00010B"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200101d"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00575"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c00739"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c04955"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c03004"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2023.100062"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00930A"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2024.110453"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.06.007"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213065"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213757"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201814711"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.134170"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400049"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-024-01675-x"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915199"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11092"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217456"},{"key":"e_1_2_8_43_1","volume":"61","author":"Yao Z. Q.","year":"2022","journal-title":"Angew. Chem. Int. Ed"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29737-z"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c02277"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010326"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.34"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja407778a"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108326"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c10628"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202421744"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.0c00477"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214539"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01317-y"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101646"},{"key":"e_1_2_8_56_1","volume":"31","author":"Zhu Z. H.","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417664"},{"key":"e_1_2_8_58_1","volume":"9","author":"Zhu Z. H.","year":"2022","journal-title":"Adv. Sci."},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.01.148"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c06046"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422517"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.4c00871"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214859"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2023.122916"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtadv.2022.100273"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c18130"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2024.11.006"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3MH01263H"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c09301"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2024.10.133"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2024.100427"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202501824","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/advs.202501824","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202501824","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T11:49:32Z","timestamp":1775908172000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202501824"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,20]]},"references-count":71,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2025,7]]}},"alternative-id":["10.1002\/advs.202501824"],"URL":"https:\/\/doi.org\/10.1002\/advs.202501824","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,20]]},"assertion":[{"value":"2025-01-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2501824"}}