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Inspired by Tillandsia leaves, which efficiently capture H<jats:sub>2<\/jats:sub>O and CO<jats:sub>2<\/jats:sub> from the air, copper nanosheets with dual\u2010functional channels are we designed: the superhygroscopic network enables capillary condensation, converting H<jats:sub>2<\/jats:sub>O(g) into H<jats:sub>2<\/jats:sub>O(l) to form H<jats:sub>2<\/jats:sub>O channels that ensure a stable supply of protons, while the CO<jats:sub>2<\/jats:sub> channels formed by the microporous structure enhance the diffusion of CO<jats:sub>2<\/jats:sub>, thus enriching the carbon source. This synergistic design creates an optimal microenvironment for CO<jats:sub>2<\/jats:sub> conversion by simultaneously delivering both protons and CO<jats:sub>2<\/jats:sub> to the reaction interface. Time\u2010of\u2010flight secondary\u2010ion mass spectroscopy (TOF\u2010SIMS), X\u2010ray absorption spectroscopy (XAS) and multiphysics simulations further reveal the designed H<jats:sub>2<\/jats:sub>O and CO<jats:sub>2<\/jats:sub> channels in the microenvironment to boost mass transports. Hence, the Faradaic efficiency (FE) for ethylene reaches up to 96% at \u2010200 mA cm<jats:sup>\u22122<\/jats:sup> with such localized triple\u2010phase interfaces, which simultaneously exhibits ultra\u2010high stability for over 170 h in the membrane electrode assembly (MEA) system. This strategy provides a construction methodology of H<jats:sub>2<\/jats:sub>O and CO<jats:sub>2<\/jats:sub> channels for improving the selectivity and stability of electrochemical CO<jats:sub>2<\/jats:sub> upgrades.<\/jats:p>","DOI":"10.1002\/advs.202502306","type":"journal-article","created":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T05:47:08Z","timestamp":1747201628000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Accelerate Mass Transport of Proton and Carbon Sources by Super\u2010Hygroscopic and Porous Nanosheets for Continuous CO<sub>2<\/sub>\u2010To\u2010Ethylene Upgrade"],"prefix":"10.1002","volume":"12","author":[{"given":"Silong","family":"Dong","sequence":"first","affiliation":[{"name":"South China Academy of Advanced Optoelectronics South China Normal University  Guangzhou Guangdong 510006 China"},{"name":"Institute of Carbon Neutrality Zhejiang Wanli University  Ningbo 315100 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