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This study reports the synthesis of a microflower\u2010like Fe@WO\n                    <jats:sub>3<\/jats:sub>\n                    \/ ZnCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    heterostructure for effective tetradecane sensing. The Fe@WO\n                    <jats:sub>3<\/jats:sub>\n                    \/ ZnCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    n\u2010p junctions demonstrated significant alterations in electrical conductivity upon exposure to tetradecane at room temperature. The sensor achieved a reasonable detection limit of 78.4\u00a0ppb and a rapid recovery time of 36\u00a0s. The remarkable sensing performance is attributed to the synergistic interactions among multiple heterojunction interfaces, doping\u2010induced active sites, the presence of oxygen vacancies, high\u2010energy crystallographic facets, reduced grain size, and enhanced crystallinity, as supported by density functional theory calculations and molecular dynamics simulations. This work identifies a promising candidate for the detection of distinct volatile organic compounds, warranting further exploration in agricultural and emission monitoring applications while addressing a critical gap in metal oxide semiconductor sensors for the detection of large\u2010molecule gases.\n                  <\/jats:p>","DOI":"10.1002\/advs.202502646","type":"journal-article","created":{"date-parts":[[2025,6,20]],"date-time":"2025-06-20T07:53:28Z","timestamp":1750406008000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Probing the Challenge of P\u2010Type Semiconductors in Long\u2010Chain VOC Detection: 3D Micro\u2010Flower Zinc Cobaltate Heterojunction Sensors"],"prefix":"10.1002","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7833-5626","authenticated-orcid":false,"given":"Kewei","family":"Liu","sequence":"first","affiliation":[{"name":"College of Mechanical Engineering Yangzhou University  Yangzhou 225127 P. 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