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However, developing carbon hollow fiber electrodes with efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    electrocatalytic performance remains unexplored and challenging. Herein, a straightforward strategy is presented to fabricate robust, self\u2010standing carbon hollow fiber electrodes modified with an unsaturated Ni\u2010N\n                    <jats:sub>2<\/jats:sub>\n                    coordination structure. This unique hollow fiber electrode configuration effectively enhances the kinetics of CO\n                    <jats:sub>2<\/jats:sub>\n                    electro\u2010conversion to CO. Both density functional theory (DFT) calculations and experimental studies reveal that the Ni\u2010N\n                    <jats:sub>2<\/jats:sub>\n                    structure significantly boosts electrocatalytic activity for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction by reducing the energy barrier for the key intermediate COOH* formation. Consequently, the electrode with unsaturated Ni\u2010N\n                    <jats:sub>2<\/jats:sub>\n                    coordination realizes a high CO Faradaic efficiency (FE) (&gt;90%) as well as a partial current density of 61 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , much superior to those of saturated Ni\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    coordination. In particular, this high performance maintains an exceptional durability for over 100 h, outperforming previously reported carbon supporting electrodes featuring Ni\u2010N\u2010C sites. This work opens new avenues for designing advanced carbon electrode structures with enhanced selectivity and activity for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction.\n                  <\/jats:p>","DOI":"10.1002\/advs.202502947","type":"journal-article","created":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T07:51:52Z","timestamp":1747727512000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Carbon Hollow Fiber Penetration Electrode with Unsaturated Ni\u2010N\n                    <sub>2<\/sub>\n                    Coordination for Enhanced CO\n                    <sub>2<\/sub>\n                    Electroreduction"],"prefix":"10.1002","volume":"12","author":[{"given":"Xiaotong","family":"Wang","sequence":"first","affiliation":[{"name":"Low\u2010Carbon Conversion Science and Engineering Center Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 P. 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China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanfang","family":"Song","sequence":"additional","affiliation":[{"name":"Low\u2010Carbon Conversion Science and Engineering Center Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. China"},{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianing","family":"Mao","sequence":"additional","affiliation":[{"name":"Low\u2010Carbon Conversion Science and Engineering Center Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 P. R. China"},{"name":"Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai 201204 P. R. 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