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However, such benefits are often achieved at the expense of either the redox potentials of the conduction and valence bands or the quantum yield due to additional electron\u2013hole recombination across the heterojunction interface. Herein, an atypical type II heterojunction constituted of Au\/TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/MFU\u20104l is reported that demonstrates outstanding catalytic performance in photocatalytic reduction of carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) to ethylene (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ) through tuning up\u2010converting of holes in MFU\u20104l component raised from full\u2010spectrum solar irradiation. Anchored to the edge of cube MFU\u20104l with a TiO\n                    <jats:sub>2<\/jats:sub>\n                    cover layer, aurum ions (Au\n                    <jats:sup>+<\/jats:sup>\n                    )supported by aurum (Au) nanoparticles enables such a reverse hole\u2010transfer event through leveraging the Ti\u2010O\n                    <jats:sup>\u2212\u2022<\/jats:sup>\n                    \u2010Au\n                    <jats:sup>+\/0<\/jats:sup>\n                    \u2010\n                    <jats:sup>\u2022\u2212<\/jats:sup>\n                    O\u2010Zn potential, which significantly accelerates the hole\u2010dominated oxidative desaturation of C\u2010C intermediates from CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction into C\u2550C bond products. The catalyst efficiently converts CO\n                    <jats:sub>2<\/jats:sub>\n                    to C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    with more than 90% selectivity and a yield of 107.0\u00a0\u00b5mol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under simulated sunlight. Electron paramagnetic resonance (EPR) experiments directly observe the holes formed in visible\u2010light excited MFU\u20104l moiety of Au\/TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/MFU\u20104l that are fused into TiO\n                    <jats:sub>2<\/jats:sub>\n                    component's holes, thereby generating more hydroxyl radicals (\u2022OH) than that TiO\n                    <jats:sub>2<\/jats:sub>\n                    is excited alone under ultraviolet (UV) carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) light of the same intensity.\n                  <\/jats:p>","DOI":"10.1002\/advs.202503336","type":"journal-article","created":{"date-parts":[[2025,5,9]],"date-time":"2025-05-09T02:48:49Z","timestamp":1746758929000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["An Atypical Heterojunction in Favor of Conversion of CO\n                    <sub>2<\/sub>\n                    and Sunlight into C\n                    <sub>2<\/sub>\n                    H\n                    <sub>4<\/sub>"],"prefix":"10.1002","volume":"12","author":[{"given":"Qin","family":"He","sequence":"first","affiliation":[{"name":"Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences Beijing National Laboratory for Molecular Sciences  Beijing 100190 P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences Beijing National Laboratory for Molecular Sciences  Beijing 100190 P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongwei","family":"Ji","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences Beijing National Laboratory for Molecular Sciences  Beijing 100190 P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. 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