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Herein, it is reported that a Ce\u2010incorporated Cu oxide (CeCuO\n                    <jats:sub>x<\/jats:sub>\n                    ) can have prominent performance for the selective production of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    with a high Faraday efficiency (FE) of 55.39% at \u22120.93 V, and partial current density of \u221239.50 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at \u22121.03 V, higher than those of Cu oxide and Cu at the same potential. Systematical experimental investigations show that the CeCuO\n                    <jats:sub>x<\/jats:sub>\n                    reconstructs to oxygen\u2010contained Cu with optimized Cu\n                    <jats:sup>0<\/jats:sup>\n                    \/(Cu\n                    <jats:sup>+<\/jats:sup>\n                    +Cu\n                    <jats:sup>2+<\/jats:sup>\n                    ) ratio and electronic structure through Ce leaching and in situ reduction. All of those benefit water molecule cleavage and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    accumulation that could provide hydrogen feedstock and suppress competitive hydrogen evolution. Importantly, specific C\n                    <jats:sub>1\u20132<\/jats:sub>\n                    intermediates generation and activation are enhanced, achieving high C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    selectivity and efficiency. Our work provides new insights into the relationship between the reconstructed structure and mechanism for boosting CO\n                    <jats:sub>2<\/jats:sub>\n                    to multi\u2010carbon products.\n                  <\/jats:p>","DOI":"10.1002\/advs.202504094","type":"journal-article","created":{"date-parts":[[2026,1,2]],"date-time":"2026-01-02T09:40:47Z","timestamp":1767346847000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Reconstructed Copper Compound by Cerium Leaching for Enhanced Electrochemical CO\n                    <sub>2<\/sub>\n                    \u2010to\u2010Ethylene Conversion"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-5176-6911","authenticated-orcid":false,"given":"Jinxian","family":"Feng","sequence":"first","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunfa","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Xuan","family":"Xiao","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lun","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keyu","family":"An","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sen","family":"Ding","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weng Fai","family":"Ip","sequence":"additional","affiliation":[{"name":"Department of Physics and Chemistry Faculty of Science and Technology University of Macau Macao SAR 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel H. 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