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However, traditional photocatalytic and thermal catalytic methods face challenges like low selectivity and yields. Herein, a novel Cu\/MoS\n                    <jats:sub>2<\/jats:sub>\n                    photothermal catalyst is synthesized via a two\u2010step hydrothermal method, anchoring single\u2010atom Cu on layered MoS\n                    <jats:sub>2<\/jats:sub>\n                    for CO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O reduction into C\n                    <jats:sub>2<\/jats:sub>\n                    products (ethanol, acetylene, and ethane). Under optimal conditions (250\u00a0\u00b0C, 903 mW\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , 320\u2013780\u00a0nm), the Cu\n                    <jats:sub>5%<\/jats:sub>\n                    \u2013MoS\n                    <jats:sub>2<\/jats:sub>\n                    catalyst achieves an ethanol yield of 3.1 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 4.6 times higher than blank MoS\n                    <jats:sub>2<\/jats:sub>\n                    . Mechanistic studies reveal that Cu improves light absorption and enhances CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and *COOH accumulation at MoS\n                    <jats:sub>2<\/jats:sub>\n                    edge S sites, as confirmed by density functional theory (DFT) calculations. Mo\u2013Cu dual sites stabilize *CHO intermediates, boosting C\n                    <jats:sub>2<\/jats:sub>\n                    product selectivity. The synergistic photothermal effect accelerates charge migration and surface reactions. This work provides cost\u2010effective insights into photothermal CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion for fuel production.\n                  <\/jats:p>","DOI":"10.1002\/advs.202504167","type":"journal-article","created":{"date-parts":[[2025,6,20]],"date-time":"2025-06-20T09:00:58Z","timestamp":1750410058000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Cu\u2012S Covalent Bonds Enable the Anchoring of Single\u2010atom Cu on Layered MoS\n                    <sub>2<\/sub>\n                    for Highly Selective and Active Photothermal Catalytic Conversion of CO\n                    <sub>2<\/sub>\n                    \u2212H\n                    <sub>2<\/sub>\n                    O to Ethanol"],"prefix":"10.1002","volume":"12","author":[{"given":"Yingao","family":"Luo","sequence":"first","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8652-2624","authenticated-orcid":false,"given":"Gaoli","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongliao","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8715-4840","authenticated-orcid":false,"given":"Sujuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiuzhen","family":"Zheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sugang","family":"Meng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0660-7773","authenticated-orcid":false,"given":"Shifu","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education College of Chemistry and Materials Science Huaibei Normal University  Huaibei Anhui 235000 P. R. 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