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However, most of these adhesives demonstrate low tolerance to extreme environments and exhibit diminished adhesion performance after cyclic adhesion testing. Herein, a hierarchical self\u2010assembly strategy is introduced for the construction of supramolecular polymer networks (poly(UIO\u2010TA)) through dynamic disulfide bond crosslinking\u2010induced assembly of metal\u2010coordinated nanoparticles (UIO\u2010TA). The UIO\u2010TA were synthesized via a stepwise coordination\u2010driven assembly process, wherein the zirconium ion coordinated with terephthalic acid and thioctic acid. Furthermore, these UIO\u2010TA were crosslinked through ring\u2010opening polymerization of dynamic disulfide bonds, resulting in the formation of poly(UIO\u2010TA). Poly(UIO\u2010TA) exhibited tough, durable, and reversible adhesion on diverse substrates, maintaining its effectiveness under mild to harsh conditions, including high temperatures (120\u00a0\u00b0C), organic solvents (e.g., dimethyl sulfoxide, ethanol), and strong acids (e.g., sulfuric acid). The adhesion performance of poly(UIO\u2010TA) is superior to poly(thioctic acid) (poly(TA)) and most reported supramolecular adhesives. These attributes can be ascribed to the synergistic interplay of metal coordination bonds, hydrogen bonds, and dynamic disulfide bonds. Notably, after the five\u2010cycle adhesion tests, the adhesion strength of poly(UIO\u2010TA) increased by \u22482.5 times, which can primarily be attributed to increased cohesion energy resulting from the further ring\u2010opening polymerization of disulfide bonds.<\/jats:p>","DOI":"10.1002\/advs.202505122","type":"journal-article","created":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T04:40:51Z","timestamp":1753936851000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Robust and Reversible Supramolecular Adhesive via Dynamic Covalent Bond Crosslinking\u2010Induced Assembly of Metal\u2010Coordinated Nanoparticles"],"prefix":"10.1002","volume":"12","author":[{"given":"Yanyan","family":"Guo","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coking Coal Resources Green Exploitation School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 P. R. 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