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Among them, quinone\u2010based compounds have attracted particular interest. Notably, compared with para\u2010quinone analogs (e.g., anthraquinone), ortho\u2010quinone\u2010based electrode materials (e.g., phenanthraquinone) demonstrate higher redox potential, which contributes to achieving higher energy density in battery applications. However, their practical applications have been limited by severe solubility in electrolytes, resulting in poor cycle performance. To improve it, two novel phenanthraquinone\u2010derived molecules, 1,4\u2010bis(9,10\u2010phenanthraquinonyl)benzene (BPQB) and 1,3,5\u2010tri(9,10\u2010phenanthraquinonyl)benzene (TPQB), are rationally designed, synthesized, and applied as cathode materials for both lithium\u2010ion batteries (LIBs) and aqueous zinc\u2010ion batteries (AZIBs). Comprehensive electrochemical evaluations reveal remarkable cycling stability and rate performance of TPQB. The TPQB cathodes for LIBs achieve a high\u2010capacity retention of 76.8% after 1,000 cycles at 5 C, while exhibiting extraordinary ultra\u2010long cycle life in AZIBs with 93.2% capacity retention over 6,000 cycles at 5 C. Their charge storage mechanisms are elucidated through various characterization methods. The work presents a novel molecular engineering strategy that effectively inhibits the dissolution of phenanthraquinone\u2010derived electrode materials and thus realizes excellent electrochemical performance across diverse battery systems.<\/jats:p>","DOI":"10.1002\/advs.202506749","type":"journal-article","created":{"date-parts":[[2025,9,11]],"date-time":"2025-09-11T09:44:40Z","timestamp":1757583880000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Molecular Engineering Empowers Phenanthraquinone Organic Cathodes with Exceptional Cycling Stability for Lithium\u2010 and Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"12","author":[{"given":"Susu","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional Materials State Key Laboratory of Advanced Materials for Intelligent Sensing Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional Materials State Key Laboratory of Advanced Materials for Intelligent Sensing Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9771-9921","authenticated-orcid":false,"given":"Jixing","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional Materials State Key Laboratory of Advanced Materials for Intelligent Sensing Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunhua","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tianjin Key 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