{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:25:23Z","timestamp":1786976723011,"version":"build-2736575974"},"reference-count":56,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2025,5,29]],"date-time":"2025-05-29T00:00:00Z","timestamp":1748476800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Hydrogel electrolyte has emerged as an effective strategy for stabilizing zinc anode. Despite certain advancements in network design, solely relying on simple combinations of traditional polymer chains or single\u2010function monomers is far from satisfactory in overcoming multiple challenges faced by zinc\u2010ion battery. Herein, a novel multifunctional monomer, benzo\u201015\u2010crown\u20105\u2010acrylamide (BCAm), is designed and introduced into hydrogel network (PBCM\u2010HE), aiming to regulate solvation sheath structure with supramolecular macrocyclic units. Specifically, rigid benzene rings in BCAm units can stabilize conformation of crown ether and bestow PBCM\u2010HE excellent mechanical properties with tensile\u2010strength of 105\u00a0kPa and compressive\u2010strength of 0.6\u00a0MPa. Critically, the locally electron\u2010rich ether bonds in supramolecular macrocycle can optimize solvation structure of hydrated zinc ions and promote ion transport, stabilizing interface interaction between electrolyte and Zn anode. Given this, PBCM\u2010HE possesses outstanding ionic conductivity (61.7 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and remarkable transference number (0.86). Besides, the Zn||PBCM\u2010HE||MnO\n                    <jats:sub>2<\/jats:sub>\n                    full cells show excellent discharge specific capacity of 290.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 C with Zn uniform deposition. This work innovatively develops a novel hydrogel electrolyte network with multifunctional monomer through one\u2010step polymerization, providing new insights and possibilities for monomer design and selection in hydrogel electrolytes, further paving the way for exploring high\u2010performance electrolytes in zinc\u2010based devices.\n                  <\/jats:p>","DOI":"10.1002\/advs.202507377","type":"journal-article","created":{"date-parts":[[2025,5,29]],"date-time":"2025-05-29T10:44:44Z","timestamp":1748515484000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Molecularly Engineered Hydrogel Electrolyte Embedded with Multifunctional Oxygen\u2010Rich Macrocyclic Units for Uniform Zinc Deposition"],"prefix":"10.1002","volume":"12","author":[{"given":"Miao","family":"Sun","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and Engineering Tianjin University  Tianjin 300350 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guochen","family":"Ji","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and Engineering Tianjin University  Tianjin 300350 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meizhi","family":"Li","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and Engineering Tianjin University  Tianjin 300350 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5446-2652","authenticated-orcid":false,"given":"Junping","family":"Zheng","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and Engineering Tianjin University  Tianjin 300350 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,29]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.39"},{"key":"e_1_2_8_2_1","volume":"64","author":"Bu F.","year":"2024","journal-title":"Angew. Chem., Int. 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