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The resulting polymeric microspheres, with a diameter of \u22482\u00a0\u00b5m, show blue to yellow\u2010green organic afterglow at room temperature. Excitingly, their phosphorescence quantum yields and lifetimes are up to 18.0% and 1.39 s, respectively, representing a breakthrough in comprehensive organic afterglow performance for polymer\u2010based luminescent microspheres. Meanwhile, dual\u2010mode organic afterglow and persistent red fluorescence with a lifetime of 0.24 s and a quantum yield of 22.2% are also achieved from the microspheres by simply replacing the guest luminogen and the phosphorescence resonance energy transfer approach, respectively. More importantly, the polymer\u2010based organic afterglow microspheres exhibit outstanding resistance to water and organic solvents. Inspired by the efficient and highly robust organic afterglow, potential applications of the polymeric microspheres are demonstrated in stretchable elastomers, information anti\u2010counterfeiting, 3D printing, and explosive detection. This work provides a universal strategy for developing polymeric microspheres with efficient, robust, and colorful organic afterglow.\n                  <\/jats:p>","DOI":"10.1002\/advs.202508888","type":"journal-article","created":{"date-parts":[[2025,7,29]],"date-time":"2025-07-29T19:29:29Z","timestamp":1753817369000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Achieving Highly Robust Polymeric Microspheres with Efficient and Full\u2010Color Organic Afterglow for 3D Printing and Anti\u2010Counterfeiting"],"prefix":"10.1002","volume":"12","author":[{"given":"Pengtao","family":"Hu","sequence":"first","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Lang","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou 510006 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