{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T12:00:35Z","timestamp":1780315235042,"version":"3.54.1"},"reference-count":44,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2025,8,13]],"date-time":"2025-08-13T00:00:00Z","timestamp":1755043200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Designing heterometallic oxygen\u2010bridge structure (M1\u2010O\u2010M2) to achieve the efficient and stable electrochemical conversion of 5\u2010hydroxymethylfurfural (HMF) to 2,5\u2010furandicarboxylic acid (FDCA) has become an important approach to address the rapid consumption of fossil fuels and mitigate white pollution. However, designing effective M1\u2010O\u2010M2 structures and elucidating their catalytic mechanisms remains a key challenge in this field. In this study, a high oxidation state V\u2010O\u2010Co structure is constructed by doping V into reconstructed CoOOH, which promotes the formation of the active intermediate V\u2010\n                    <jats:sup>*<\/jats:sup>\n                    O. The catalyst achieves a low HMF oxidation onset potential of 1.13 V vs. RHE, the HMF conversion rate reaches 99.6%, the FDCA selectivity reaches 97.8%, and the Faradaic efficiency reaches 97.0% at an applied potential of 1.30 V vs. RHE. Based on this novel design strategy, V\u2010doped Ni\n                    <jats:sub>2<\/jats:sub>\n                    P\/NF is further constructed, which also forms the active intermediate V\u2010\n                    <jats:sup>*<\/jats:sup>\n                    O, validating the effectiveness of this strategy. Notably, the oxidation state\u2010controlled V\u2010O\u2010Co structure demonstrates excellent catalytic performance in promoting the efficient conversion of various organic compounds (such as glycerol, glucose, methanol, etc.) into high\u2010value chemicals, providing a precedent for the development of single hetero\u2010oxygen\u2010bridge structures for the effective conversion of various high\u2010value compounds.\n                  <\/jats:p>","DOI":"10.1002\/advs.202508912","type":"journal-article","created":{"date-parts":[[2025,8,13]],"date-time":"2025-08-13T12:20:26Z","timestamp":1755087626000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["High Oxidation State V\u2010O\u2010Co Structure Promotes the Role of V\u2010\n                    <sup>*<\/sup>\n                    O Intermediates in Efficient HMF Oxidation"],"prefix":"10.1002","volume":"12","author":[{"given":"Honglei","family":"Wang","sequence":"first","affiliation":[{"name":"College of Chemical Engineering and Technology Key Laboratory of Catalytic Conversion Energy Coupling in Shanxi Province Taiyuan University of Science and Technology  Taiyuan 030024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue","family":"Wen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering School of Electronics Information and Electrical Engineering Shanghai Jiao Tong University  Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiuxiang","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering School of Electronics Information and Electrical Engineering Shanghai Jiao Tong University  Shanghai 200240 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