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They have been applied in many catalytic fields and have shown excellent catalytic activity, such as oxygen reduction reaction (ORR) and carbon dioxide reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR), etc. The application of these complexes in electrocatalytic nitrogen fixation, such as nitrogen reduction reactions (NRR), nitrate reduction reactions (NO\n                    <jats:sub>3<\/jats:sub>\n                    RR), nitrite reduction reactions (NO\n                    <jats:sub>2<\/jats:sub>\n                    RR), and nitrate\/nitrite\/nitrogen\u2010carbon dioxide co\u2010reduction (N\n                    <jats:sub>2<\/jats:sub>\n                    \/NO\n                    <jats:sub>x<\/jats:sub>\n                    \u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) for urea production, has been emphasized in recent years. The main obstacles for these complexes to function effectively as electrocatalysts involve the necessity for a well\u2010thought\u2010out design of porphyrin\/phthalocyanine structures and a more comprehensive understanding of their structure\u2010activity relationships. This review summarizes the modifying porphyrin\/phthalocyanine complex methods, constructing derivative strategies, and exploring the relevant electrocatalytic reaction mechanisms and their applications for electrocatalytic nitrogen fixation. Optimization strategies based on reaction mechanisms and catalytic performance are proposed. Finally, this comprehensive overview aims to provide professional insights that will guide future experimental and theoretical advancements in porphyrin\/phthalocyanine complexes and highlight their challenges and prospects for electrocatalytic systems.\n                  <\/jats:p>","DOI":"10.1002\/advs.202509323","type":"journal-article","created":{"date-parts":[[2025,9,12]],"date-time":"2025-09-12T03:32:51Z","timestamp":1757647971000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Metalloporphyrin\/Phthalocyanine Catalysts for Electrocatalytic Nitrogen Fixation"],"prefix":"10.1002","volume":"12","author":[{"given":"Hai","family":"Sun","sequence":"first","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4287-0779","authenticated-orcid":false,"given":"Shun","family":"Lu","sequence":"additional","affiliation":[{"name":"Chongqing Institute of Green and Intelligent Technology Chinese Academy of Sciences  Chongqing 400714 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanyuan","family":"Qi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahui","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Terence","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Construction Engineering Northumbria University  Newcastle upon Tyne NE1 8ST UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun\u2010Sheng","family":"Qin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heng","family":"Rao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun Jilin 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,11]]},"reference":[{"key":"e_1_2_10_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nrmicro.2018.9"},{"key":"e_1_2_10_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1136674"},{"key":"e_1_2_10_1_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00833-z"},{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2021.01.029"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10533-004-0370-0"},{"key":"e_1_2_10_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00611"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar6611"},{"key":"e_1_2_10_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00857A"},{"key":"e_1_2_10_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305462"},{"key":"e_1_2_10_4_4","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c05373"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1186120"},{"key":"e_1_2_10_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature06592"},{"key":"e_1_2_10_5_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41579-022-00687-z"},{"key":"e_1_2_10_5_4","doi-asserted-by":"crossref","DOI":"10.1126\/science.abh3767","volume":"376","author":"Mason R. 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