{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T12:03:13Z","timestamp":1784894593242,"version":"3.55.0"},"reference-count":49,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2025,9,14]],"date-time":"2025-09-14T00:00:00Z","timestamp":1757808000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    To address the challenge of uneven distribution of metal\u2013organic frameworks (MOFs) within the membrane in oil\u2010water separation, this study demonstrates a novel copper (II) benzene\u20101,3,5\u2010tricarboxylate (CuBTC) embedded fluorinated composite membrane fabricated through high internal phase emulsion (HIPE) templating. During polymerization, MOFs spontaneously align at porous matrix interfaces via interfacial confinement, effectively suppressing particle aggregation. The resultant MOF\u2010polymer composite membranes exhibit some critical advantages: ultrafast oil\u2010water separation kinetics (60,854.4 L\u00b7m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7bar\n                    <jats:sup>\u22121<\/jats:sup>\n                    for n\u2010hexane); chemical stability in extreme pH environments (pH 1\u201312). Molecular dynamics simulations revealed a unique separation mechanism dominated by synergistic electrostatic repulsion\u2010based CuBTC and the fluoro\u2010polymer matrix, challenging the conventional requirement of superhydrophobicity for efficient separation. The optimized membrane achieved 99.4% separation efficiency with &lt;2% performance decay over 20 cycles. Furthermore, a universal flux\u2010thickness correlation (\n                    <jats:italic>J<\/jats:italic>\n                    \u2005 = \u2005\n                    <jats:italic>Ae<\/jats:italic>\n                    <jats:sup>\n                      \u2212\n                      <jats:italic>T<\/jats:italic>\n                      \/\n                      <jats:italic>B<\/jats:italic>\n                    <\/jats:sup>\n                    +\n                    <jats:italic>C<\/jats:italic>\n                    ) enabling quantitative comparison of separation membranes independent of thickness variations is established.\n                  <\/jats:p>","DOI":"10.1002\/advs.202509657","type":"journal-article","created":{"date-parts":[[2025,9,14]],"date-time":"2025-09-14T08:21:30Z","timestamp":1757838090000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Freestanding CuBTC\u2010Doped Fluorine\u2010Containing Flexible Membrane with Ultrafast Oil\u2010Water Separation via Enhanced Electrostatic Repulsion Force"],"prefix":"10.1002","volume":"12","author":[{"given":"Xiaoshuang","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peize","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minghui","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boyu","family":"Lei","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5083-4220","authenticated-orcid":false,"given":"Bing","family":"Geng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanghui","family":"Cui","sequence":"additional","affiliation":[{"name":"Drilling Fluid Research Center of Mud Service Branch Bohai Drilling Engineer Company China National Petroleum Corporation (CNPC)  Tianjin 300280 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan 250022 China"},{"name":"Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,14]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA04469B"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2023.102971"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2022.107532"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA02202F"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402527"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c00158"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2024.111908"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609295"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.127004"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.124412"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.78"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00291-2"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00031H"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.130134"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2023.172897"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.0c00980"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.54506"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jwpe.2023.104676"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15081950"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/B711844A"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201204520"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abe0192"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104487"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04152G"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801350"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149338"},{"key":"e_1_2_8_27_1","volume":"476","author":"Kumar S.","year":"2023","journal-title":"Chem. Rev."},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04073"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09950"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2021.130109"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cherd.2023.01.005"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2023.121655"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.3c00331"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.desal.2021.115536"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2020.117256"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2023.121820"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jwpe.2023.103997"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.126691"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2023.103778"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4NJ00142G"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfcoat.2020.126344"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c04580"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2022.117695"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149991"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI01613K"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c05837"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2020.110070"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c18825"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/pi.6574"}],"container-title":["Advanced Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/advs.202509657","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,1,5]],"date-time":"2026-01-05T09:58:38Z","timestamp":1767607118000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/advs.202509657"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,14]]},"references-count":49,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,12]]}},"alternative-id":["10.1002\/advs.202509657"],"URL":"https:\/\/doi.org\/10.1002\/advs.202509657","archive":["Portico"],"relation":{},"ISSN":["2198-3844","2198-3844"],"issn-type":[{"value":"2198-3844","type":"print"},{"value":"2198-3844","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,14]]},"assertion":[{"value":"2025-05-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e09657"}}