{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T04:17:21Z","timestamp":1790828241010,"version":"4.1.0"},"reference-count":48,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2025,9,14]],"date-time":"2025-09-14T00:00:00Z","timestamp":1757808000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22476170"],"award-info":[{"award-number":["22476170"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Breaking the symmetric structure of active centers to adjust their electronic structure is a promising strategy for improving the performance of single\u2010atom catalysts (SACs) in electrocatalytic carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction (ECR). However, it remains highly challenging to achieve precise regulation and fine\u2010tuning of single\u2010atom sites at the atomic level. Here, by introducing S and Cl atoms, a Zn\u2010SAC (ZnN\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>1<\/jats:sub>\n                    Cl\/C) with coupled axial and asymmetric coordination is successfully constructed, thereby enhancing the ECR performance. In situ attenuated total reflection infrared spectroscopy demonstrates that ZnN\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>1<\/jats:sub>\n                    Cl\/C promotes the formation of\n                    <jats:sup>*<\/jats:sup>\n                    COOH and the desorption of\n                    <jats:sup>*<\/jats:sup>\n                    CO species. Theoretical calculations show that the asymmetric coordination of S and the axial coordination of Cl can lead to the electron redistribution near the single Zn sites, increasing the overlap between the Zn (3d) and\n                    <jats:sup>*<\/jats:sup>\n                    COOH (2p) orbitals. This enhances the adsorption strength of\n                    <jats:sup>*<\/jats:sup>\n                    COOH on the Zn site and reduces the desorption energy of\n                    <jats:sup>*<\/jats:sup>\n                    CO, thus facilitating catalytic performance. Therefore, the ZnN\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>1<\/jats:sub>\n                    Cl\/C catalyst achieves a CO faradaic efficiency of \u2248100% in an H\u2010cell, with excellent long\u2010term stability of 240 h. This work may pave the way for the development of efficient ECR catalysts via fine manipulation of asymmetric and electronic structures of single\u2010atom metal sites.\n                  <\/jats:p>","DOI":"10.1002\/advs.202509698","type":"journal-article","created":{"date-parts":[[2025,9,14]],"date-time":"2025-09-14T08:07:11Z","timestamp":1757837231000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Axial and Asymmetric Coordination Coupling Adjust the Electronic Structure of Single\u2010Atom Zinc Sites for Efficient Electroreduction of Carbon Dioxide"],"prefix":"10.1002","volume":"12","author":[{"given":"Cao","family":"Guo","sequence":"first","affiliation":[{"name":"Xinjiang Key Laboratory of Novel Functional Materials Chemistry College of Chemistry and Environmental Sciences Kashi University  Kashi 844000 China"},{"name":"Qilu Lake Field Scientific Observation and Research Station for Plateau Shallow Lake in Yunnan Province Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental Science Yunnan University  Kunming 650504 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Wang","sequence":"additional","affiliation":[{"name":"Xinjiang Key Laboratory of Novel Functional Materials Chemistry College of Chemistry and Environmental Sciences Kashi University  Kashi 844000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdukader","family":"Abdukayum","sequence":"additional","affiliation":[{"name":"Xinjiang Key Laboratory of Novel Functional Materials Chemistry College of Chemistry and Environmental Sciences Kashi University  Kashi 844000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingde","family":"Chen","sequence":"additional","affiliation":[{"name":"Qilu Lake Field Scientific Observation and Research Station for Plateau Shallow Lake in Yunnan Province Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental Science Yunnan University  Kunming 650504 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengqin","family":"Chang","sequence":"additional","affiliation":[{"name":"Qilu Lake Field Scientific Observation and Research Station for Plateau Shallow Lake in Yunnan Province Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental Science Yunnan University  Kunming 650504 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyi","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi 830017 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuguang","family":"An","sequence":"additional","affiliation":[{"name":"School of Mechanical Engineering Chengdu University  Chengdu 610106 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangzhi","family":"Hu","sequence":"additional","affiliation":[{"name":"Xinjiang Key Laboratory of Novel Functional Materials Chemistry College of Chemistry and Environmental Sciences Kashi University  Kashi 844000 China"},{"name":"Qilu Lake Field Scientific Observation and Research Station for Plateau Shallow Lake in Yunnan Province Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental Science Yunnan University  Kunming 650504 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6671-4650","authenticated-orcid":false,"given":"Yujie","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester M13 9PL 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